188345-42-8

Basic information

• Product Name: trimethyl 3,6-cyclohexadiene-1,2,3-tricarboxylate
• Synonyms: trimethyl 3,6-cyclohexadiene-1,2,3-tricarboxylate
• CAS NO: 188345-42-8
• Molecular Weight: 254.24
• Mol File: 188345-42-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trimethyl 3,6-cyclohexadiene-1,2,3-tricarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: trimethyl 3,6-cyclohexadiene-1,2,3-tricarboxylate(188345-42-8)
• EPA Substance Registry System: trimethyl 3,6-cyclohexadiene-1,2,3-tricarboxylate(188345-42-8)

Safety Data

• Hazardous Substances Data: 188345-42-8(Hazardous Substances Data)

Upstream product

• 624-48-6 dimethyl cis-but-2-ene-1,4-dioate 
• 187808-48-6 methyl 5-(N,N-dimethylamino)-2,4-pentadienoate 
• 623-43-8 crotonic acid methyl ester 
• 624-49-7 dimethylfumarate 

Downstream Products

• 2672-57-3 benzene-1,2,3-tricarboxylic acid trimethyl ester 

Relevant articles and documents

Aminodienylesters. I: The cycloaddition reactions of tert- aminodienylester with α,β-unsaturated carbonyl compounds, styrenes, and quinones

Methyl 5-(N,N-dimethylamino)-2,4-pentadienoate (tert-aminodienylester 1) was synthesized by condensation of methyl crotonate (2) with N,N,N',N'- tetramethylenediamine (3). The reactivity of 1 was investigated with methyl propiolate (4), dimethyl 2-butynedionate (5), dimethyl maleate (6), dimethyl fumarate (7), 2-buten-4-olide (8), 2-cyclohexenone (9), styrene (10), trans- β-nitrostyrene (11), 1,4-benzoquinone (19), methyl 1,4-naphthoquinone-5- carboxylate (21), 1,4-naphthoquinone (24), juglone (26), 5-methoxy-1,4- naphthoquinone (28), naphthazarin (31), and naphthazarin dimethyl ether (33). In addition, 5-(N,N-dimethylamino)-2,4-pentadienenitrile (tert-aminodienyl- nitrile 37) was synthesized by condensation of crotononitrile (36) with 3. The reactivity of 37 was investigated with dimethyl 2-butynedionate (5), and 2-cyclohexenone (9).