188637-84-5

Basic information

• Product Name: [copper(I)(tris(2-pyridylmethyl)amine)]⁽¹⁺⁾
• Synonyms: [copper(I)(tris(2-pyridylmethyl)amine)]⁽¹⁺⁾
• CAS NO: 188637-84-5
• Molecular Weight: 353.914
• Mol File: 188637-84-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [copper(I)(tris(2-pyridylmethyl)amine)]⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: [copper(I)(tris(2-pyridylmethyl)amine)]⁽¹⁺⁾(188637-84-5)
• EPA Substance Registry System: [copper(I)(tris(2-pyridylmethyl)amine)]⁽¹⁺⁾(188637-84-5)

Safety Data

• Hazardous Substances Data: 188637-84-5(Hazardous Substances Data)

Upstream product

• 10102-43-9 nitrogen(II) oxide 

Relevant articles and documents

Copper(I)/NO(g) Reductive Coupling Producing a trans-Hyponitrite Bridged Dicopper(II) Complex: Redox Reversal Giving Copper(I)/NO(g) Disproportionation

A copper complex, [CuI(tmpa)(MeCN)]+, effectively reductively couples NO(g) at RT in methanol (MeOH), giving a structurally characterized hyponitrito-dicopper(II) adduct. Hydrogen-bonding from MeOH is critical for the hyponitrite complex formation and stabilization. This complex exhibits the reverse redox process in aprotic solvents, giving CuI + NO(g), leading to CuI-mediated NO(g)-disproportionation. The relationship of this chemistry to biological iron and/or copper mediated NO(g) reductive coupling to give N2O(g) is discussed.