188713-26-0Relevant articles and documents
An asymmetric dinuclear copper(II) complex with phenoxo and acetate bridges: Synthesis, structure and magnetic studies
Dutta, Gorachand,Debnath, Rajib Kumar,Kalita, Apurba,Kumar, Pankaj,Sarma, Moushumi,Shankar, R. Boomi,Mondal, Biplab
, p. 293 - 298 (2011)
The dinuclear (μ2-acetate)bis(μ2-phenoxide)di- copper(II) complex, 1 with a tetradentate ligand, L (L = 2,4-di-tert-butyl-6- {[(2-dimethylaminoethyl)-(2-hydroxybenzyl)-amino]-methyl}-phenol) has been synthesized and characterized. The single crystal X-ray structure of the dinuclear complex was determined. Variable temperature magnetic susceptibility measurement showed that the two copper(II) centres are strongly anti-ferromagnetically coupled. The structural study revealed that the Cu-Cu distance (2.911 ) is very close to the distance observed in dinuclear copper(II) acetate. The average Cu-O-Cu angles (~87°) are found to be the lowest amongst the examples reported so far.
Mononuclear and Mixed-Valence Trinuclear Manganese Complexes Containing Tripodal Tetradentate Ligands. Phenolato, Carboxylato, and Alkoxo Bridges
Hirotsu, Masakazu,Kojima, Masaaki,Yoshikawa, Yuzo
, p. 649 - 657 (2007/10/03)
Manganese complexes containing tripodal tetradentate ligands with an N2O2 donor set (H2L1: N,N-bis(2-hydroxybenzyl)-N′,N′-dimethylethylenediamine, H2L2: N-(3,5-di-t-butyl-2-hydroxybenzyl)-N