188983-80-4

Basic information

• Product Name: Nickel, [bis[bis(trimethylsilyl)amino]germylene]bis(triphenylphosphine)-
• CAS NO: 188983-80-4
• Molecular Formula: C48H66GeN2NiP2Si4
• Molecular Weight: 976.635
• Mol File: 188983-80-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Nickel, [bis[bis(trimethylsilyl)amino]germylene]bis(triphenylphosphine)-(CAS DataBase Reference)
• NIST Chemistry Reference: Nickel, [bis[bis(trimethylsilyl)amino]germylene]bis(triphenylphosphine)-(188983-80-4)
• EPA Substance Registry System: Nickel, [bis[bis(trimethylsilyl)amino]germylene]bis(triphenylphosphine)-(188983-80-4)

Safety Data

• Hazardous Substances Data: 188983-80-4(Hazardous Substances Data)

Upstream product

• 1295-35-8 bis(1,5-cyclooctadiene)nickel ⁽⁰⁾ 
• 59863-12-6 bis[bis(trimethylsilyl)amino]germanium(II) 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

Transition metal germylene complexes as hydrogenation catalysts: The synthesis of a rare bis(amino)germane

Mild conditions avoid the common problem of Ge-N bond scission in the stoichiometric and catalytic synthesis of a rare example of a stable bis(amino)germane from Group 10 metal - germylene complexes [Eq. (a), R = Et, Ph]. The reaction generates an interesting GeH2 building block.