189252-18-4

Basic information

• Product Name: Benzenamine, 4-bromo-2-(1-phenylethenyl)-
• CAS NO: 189252-18-4
• Molecular Formula: C14H12BrN
• Molecular Weight: 274.16
• Mol File: 189252-18-4.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-bromo-2-(1-phenylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-bromo-2-(1-phenylethenyl)-(189252-18-4)
• EPA Substance Registry System: Benzenamine, 4-bromo-2-(1-phenylethenyl)-(189252-18-4)

Safety Data

• Hazardous Substances Data: 189252-18-4(Hazardous Substances Data)

Upstream product

• 857550-48-2 1-(2-amino-5-bromo-phenyl)-1-phenyl-ethanol 
• 536-74-3 phenylacetylene 
• 106-40-1 4-bromo-aniline 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 39859-36-4 2-amino-5-bromobenzophenone 
• 39263-32-6 2-amino-5-bromobenzonitrile 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 100-58-3 phenylmagnesium bromide 
• 108-86-1 bromobenzene 
• 29124-56-9 1-(2-amino-5-bromophenyl)ethanone 

Downstream Products

• 1220166-75-5 C₁₈H₁₆BrN 
• 1346155-02-9 C₂₄H₂₂BrN 
• 1346155-07-4 N-benzyl-6-bromo-4-phenyl-2-quinolone 
• 54470-19-8 5-bromo-3-phenyl-1H-indole 
• 861872-54-0 6-bromo-4-phenylquinoline 
• 1217862-75-3 methyl 5-bromo-3-phenyl-1H-indole-2-carboxylate 
• 73402-93-4 6-bromo-2,4-diphenylquinoline 

Relevant articles and documents

Br?nsted Acid-Catalyzed Synthesis of N-Arylindoles from 2-Vinylanilines and Quinones

In the presence of a quinone, Br?nsted acid-catalyzed intramolecular C?N bond formation of o-vinylanilines by electrophilic cyclization was developed, giving the corresponding N-arylindoles in good to high yields. The reaction worked well for o-vinylanilines with terminal and internal C=C double bonds.

PEG-400 as a carbon synthon: Highly selective synthesis of quinolines and methylquinolines under metal-free conditions

A metal-free, peroxide-free, and efficient procedure for the highly selective synthesis of quinolines and methylquinolines was reported. The main feature of this method was that the same substrate can produce quinolines and methylquinolines, respectively, under different reaction conditions. PEG-400 was used as both a reactant and solvent in this reaction. The utility of the designed procedure was also demonstrated by the derivatization of the products to bioactive compounds. This journal is

Ir(iii)-Catalysed electrooxidative intramolecular dehydrogenative C-H/N-H coupling for the synthesis of N-H indoles

Herein, an iridium(iii)-catalysed electrooxidative intramolecular dehydrogenative C-H/N-H coupling of unprotected 2-alkenyl anilines is described. The developed method allows the synthesis of a variety of 3-substituted N-H indole scaffolds under undivided electrolytic conditions. Mechanistic studies suggest that the reaction proceeds through the electro-oxidation induced reductive elimination pathway.