18944-91-7

Basic information

• Product Name: Benzoic acid (2S,3R,4S,5R,6S)-2-bromomethyl-4,5-bis-methanesulfonyloxy-6-methoxy-tetrahydro-pyran-3-yl ester
• Synonyms: Benzoic acid (2S,3R,4S,5R,6S)-2-bromomethyl-4,5-bis-methanesulfonyloxy-6-methoxy-tetrahydro-pyran-3-yl ester
• CAS NO: 18944-91-7
• Molecular Weight: 517.373
• Mol File: 18944-91-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzoic acid (2S,3R,4S,5R,6S)-2-bromomethyl-4,5-bis-methanesulfonyloxy-6-methoxy-tetrahydro-pyran-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (2S,3R,4S,5R,6S)-2-bromomethyl-4,5-bis-methanesulfonyloxy-6-methoxy-tetrahydro-pyran-3-yl ester(18944-91-7)
• EPA Substance Registry System: Benzoic acid (2S,3R,4S,5R,6S)-2-bromomethyl-4,5-bis-methanesulfonyloxy-6-methoxy-tetrahydro-pyran-3-yl ester(18944-91-7)

Safety Data

• Hazardous Substances Data: 18944-91-7(Hazardous Substances Data)

Upstream product

• 6619-12-1 methyl 4,6-O-benzylidene 2,3-di-O-mesylate-α-D-glucose 
• 65530-21-4 methyl 4,6-O-benzylidene-2,3-di-O-methanesulfonyl-α-D-glucopyranoside 

Relevant articles and documents

Facile bromination of o-benzylidene sugar and thf ethers with NBS in chloroform in the presence of AIBN

N-Bromosuccinimide in chloroform in the presence of a catalytic amount of AIBN is found to cleave O-benzylidene sugar into bromobenzoate in efficient manner. THP-ethers were cleaved into bromides and bromo-esters in high yield.