19093-37-9

Basic information

• Product Name: ALLYL PHENYL SULFOXIDE
• Synonyms: ALLYL PHENYL SULFOXIDE;(allylsulphinyl)benzene;ALLYL PHENYL SULFOXIDE, TECH.;(2-Propenylsulfinyl)benzene;(Allylsulfinyl)benzene;Phenyl (2-propenyl) sulfoxide;Phenyl allyl sulfoxide;Einecs 242-811-4
• CAS NO: 19093-37-9
• Molecular Formula: C₉H₁₀OS
• Molecular Weight: 166.24
• EINECS: 242-811-4
• Product Categories: monomer
• Mol File: 19093-37-9.mol
• Article Data: 158

Chemical Properties

• Boiling Point: 85 °C0.3 mm Hg(lit.)
• Flash Point: 133.2°C
• Appearance: /
• Density: 1.122 g/mL at 20 °C(lit.)
• Vapor Pressure: 0.0025mmHg at 25°C
• Refractive Index: n20/D 1.578
• CAS DataBase Reference: ALLYL PHENYL SULFOXIDE(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYL PHENYL SULFOXIDE(19093-37-9)
• EPA Substance Registry System: ALLYL PHENYL SULFOXIDE(19093-37-9)

Safety Data

• Hazard Codes: Xn
• Statements: 20/21
• Safety Statements: 23-36/37
• WGK Germany: 3
• Hazardous Substances Data: 19093-37-9(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Synthesis, p. 815, 1983 DOI: 10.1055/s-1983-30526Tetrahedron Letters, 35, p. 1413, 1994 DOI: 10.1016/S0040-4039(00)76232-0

InChI:InChI=1/C9H10OS/c1-2-8-11(10)9-6-4-3-5-7-9/h2-7H,1,8H2

Upstream product

• 5296-64-0 allyl phenyl thioether 
• 107-18-6 allyl alcohol 
• 931-59-9 benzenesulfenyl chloride 
• 137956-96-8 Prop-2-ene-1-sulfinic acid (R)-((1S,2R)-2-hydroxy-1-methyl-2-phenyl-ethyl)-methyl-amide 
• 67652-99-7 (+/-)_S-(E)-1-(phenylsulfinyl)prop-1-ene 
• 92838-57-8 benzenesulfinic acid allyl ester 
• 108-98-5 thiophenol 
• 670-98-4 methyl benzenesulfinate 
• 882-33-7 diphenyldisulfane 
• 4972-29-6 benzenesulphinyl chloride 
• 1208-20-4 S-phenyl benzenethiosulfinate 
• 2622-05-1 allylmagnesium bromide 
• 6099-23-6 1-(phenylsulfinyl)acetophenone 
• 106-95-6 allyl bromide 

Downstream Products

• 37909-04-9 Phenyltrithioperacetat 
• 77548-22-2 1-(3-oxocyclopentyl)-3-phenylsulfinyl-2-(E)-propene 
• 114678-83-0 (2'E)-4,4a,5,6,7,8-hexahydro-4a-methyl-2'-<3'-(phenylsulfinyl)prop-2'-enyl>-2(3H)-naphthalenol 
• 105214-34-4 (E and Z)-2-(3-(phenylthio)prop-2-en-1-yl)cyclohexanone 
• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 54234-79-6 propyl phenyl sulfoxide 
• 16212-05-8 (allylsulfonyl)benzene 
• 54234-79-6 (R)-(propylsulfinyl)benzene 
• 109120-75-4 phenyl n-propyl sulfoxide 
• 153092-46-7 allyl(imino)(phenyl)-λ⁶-sulfanone 
• 17277-58-6 methyl (phenylsulfanyl)acetate 
• 72024-41-0 S-phenyl benzylcarbamothioate 

Relevant articles and documents

Chemoselective Method for the Preparation of Phenyl Sulfoxides by the Oxidation of Phenyl Sulfides with 2-Hydroperoxy-2-methoxypropane

Phenyl sulfoxides are easily prepared by the chemoselective oxidation of the corresponding sulfides with molecular equivalents of 2-hydroperoxy-2-methoxypropane.This reagent is generated from 2,3-dimethyl-2-butene by ozonization in methanol.

Selective oxidation of sulfides to sulfoxides using IBX-esters

IBX-esters (esters of 2-iodoxybenzoic acid) are convenient hypervalent iodine reagents for the clean and selective oxidation of organic sulfides to sulfoxides. This reaction proceeds without over-oxidation to sulfones and is compatible with the presence of the hydroxy group, double bond, phenol ether, benzylic carbon, and various substituted phenyl rings in the molecule of the substrate.

Polyoxometalate-Based Organic-Inorganic Hybrids as Heterogeneous Catalysts for Cycloaddition of CO2with Epoxides and Oxidative Desulfurization Reactions

Self-assembly of polyoxometalates, transition metal salts, and 2,6-bis(2′-pyridyl)-4-hydroxypyridine (LOH) obtained four organic-inorganic hybrids [Co2.5(LOH)(LO)2(H2O)2(PW12O39)]·3CH3CN·2OH (1), [Zn1.5(LOH)3]·(PMo12O40)·CH3OH·2H2O (2), [Cd1.5(LOH)3]·(PW12O40)·2CH3OH·1.5H2O (3), and [Mn(LOH)2]·(PW12O40)·2CH3CN·H3O (4). Hybrid 1 exhibits an extended chain, which could be further connected into a 3D supramolecular architecture by H-bonds. Hybrids 2-4 feature monomolecular structures, which are further bridged via H-bonds to yield charming 3D supramolecular structures. Noteworthy, 1 and 2 can be employed as recyclable and highly efficient heterogeneous catalysts. The activated 1 displays a high catalytic activity for the cycloaddition reaction of CO2 and epoxides. Hybrid 2 exhibits an excellent catalytic performance for the oxidative desulfurization reaction.

Selective and mild sulfoxidation of 2-sulfylbenzothiazole using hydroperoxides derived from cyclohexanone in the absence of catalyst

Alkyl hydroperoxides derived from cyclohexanone are attractive oxidants because they are easily available, more reactive than TBHP but much less acidic than m-CPBA. Wherein 1,1′-peroxybis(1-hydroperoxycyclohexane) (C) can be generated by the current simply method and displays the excellent reactivity and selectivity based on oxidative reactions of various benzothiazolyl sulfides substituted by different function groups. The research found that the reactions can be performed in the absence of catalyst and under very mild conditions optimized. Yields of sulfoxides is higher than 90%, no or a little reaction happened at the proximal double bond、 N and S atoms in the benzothiazolyl moiety. Phenyl sulfide as the substrates was also examined for the reaction scope test. The results show that they were uniquely and completely oxidized to sulfoxides in 1 h. A mild, environmentally friendly, catalyst-free aryl sulfide sulfoxidation method has been developed.