191590-16-6

Basic information

• Product Name: [Ru(2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(Cl)2]Cl
• CAS NO: 191590-16-6
• Molecular Weight: 676.03
• Mol File: 191590-16-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ru(2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(Cl)2]Cl(CAS DataBase Reference)
• NIST Chemistry Reference: [Ru(2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(Cl)2]Cl(191590-16-6)
• EPA Substance Registry System: [Ru(2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(Cl)2]Cl(191590-16-6)

Safety Data

• Hazardous Substances Data: 191590-16-6(Hazardous Substances Data)

Upstream product

• 10049-08-8 ruthenium(III)chloride 
• 79403-78-4 2,3,8,9‐tetraphenyl‐1,4,7,10‐tetraazacyclododeca‐1,3,7,9‐tetraene 

Relevant articles and documents

Synthesis and spectral studies of platinum group metal complexes of three twelve-membered tetradentate macrocyclic ligands

Platinum group metal complexes of the general compositions M(Ligand)Cl3 [M = Ru(III), Ir(III)] and M(Ligand)Cl2 [M = Pd(II), Pt(II) have been synthesized [Ligand = 2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene(L 1), dibenzo[e,k]-2,3,-tetraphenyl-1,4,710-tetraazacyclododeca-1,3,7,9- tetraene (L2) and dibenzo[e,k]-2,3,8,9-tetramethyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene (L3)]. The complexes have been characterized on the basis of elemental analyses, molar conductance, magnetic susceptibility measurements and electronic spectral studies. Sharp bands were observed in the electronic spectra of the complexes. The 8 values could not be reported as the spectra and been recorded in Nujol mulls. The Ru(III) and Ir(III) complexes have been found to stabilize an octahedral geometry while a square-planar geometry is assigned to the Pd(II) and Pt(II) complexes.