1917-05-1Relevant articles and documents
Cyanuric chloride as promoter for the oxidation of sulfides and deoxygenation of sulfoxides
Bahrami, Kiumars,Khodaei, Mohammad M.,Sohrabnezhad, Samira
, p. 6420 - 6423 (2011)
This Letter discusses the use of cyanuric chloride as an efficient promoter for the chemoselective oxidation of sulfides to the corresponding sulfones in the presence of H2O2 as the terminal oxidant. Sulfoxides were also found to undergo deoxygenation to sulfides with cyanuric chloride and potassium iodide system. The reaction is broad in scope and easy to perform.
TAPC-promoted oxidation of sulfides and deoxygenation of sulfoxides
Bahrami, Kiumars,Khodaei, Mohammad M.,Sheikh Arabi, Mehdi
supporting information; experimental part, p. 6208 - 6213 (2010/11/04)
Figure presented. 1,3,5-Triazo-2,4,6-triphosphorine-2,2,4,4,6,6- tetrachloride (TAPC) was found to be an efficient promoter for the oxidation of sulfides and deoxygenation of sulfoxides. Excellent yields, short reaction time, easy and quick isolation of the products, solvent-free process, and excellent chemoselectivity are the main advantages of this procedure.
