191721-03-6

Basic information

• Product Name: (Z)-N-benzyl-(3-O-benzyl-1,2-O-isopropylidene-5-deoxy-α-D-ribofuranos-5-ylidene)amine N-oxide
• Synonyms: (Z)-N-benzyl-(3-O-benzyl-1,2-O-isopropylidene-5-deoxy-α-D-ribofuranos-5-ylidene)amine N-oxide
• CAS NO: 191721-03-6
• Molecular Weight: 383.444
• Mol File: 191721-03-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (Z)-N-benzyl-(3-O-benzyl-1,2-O-isopropylidene-5-deoxy-α-D-ribofuranos-5-ylidene)amine N-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-N-benzyl-(3-O-benzyl-1,2-O-isopropylidene-5-deoxy-α-D-ribofuranos-5-ylidene)amine N-oxide(191721-03-6)
• EPA Substance Registry System: (Z)-N-benzyl-(3-O-benzyl-1,2-O-isopropylidene-5-deoxy-α-D-ribofuranos-5-ylidene)amine N-oxide(191721-03-6)

Safety Data

• Hazardous Substances Data: 191721-03-6(Hazardous Substances Data)

Upstream product

• 63593-02-2 3-O-benzyl-1,2-O-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose 
• 29601-98-7 N-benzylhydroxylamine hydrochloride 

Downstream Products

• 191721-04-7 N-Benzyl-N-[(S)-1-((3aR,5R,6R,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethyl]-hydroxylamine 
• 191721-05-8 N-Benzyl-N-[(R)-1-((3aR,5R,6R,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethyl]-hydroxylamine 
• 191721-01-4 N-Benzyl-N-[(S)-1-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethyl]-hydroxylamine 
• 191721-06-9 3-O-benzyl-5-benzylamino-5,6-dideoxy-1,2-O-isopropylidene-β-L-ido-1,4-furanose 
• 72369-68-7 (E)-5,6-didehydro-5,6-dideoxy-3-O-benzyl-1,2-O-isopropylidene-α-D-ribo-heptodialo-1,4-furanose 

Relevant articles and documents

Regio- and stereoselective synthesis of 3- and 5-(C-glycosyl)-4- nitroisoxazolidines by nitrone-nitroalkene [3+2] cycloaddition reactions

Cycloaddition reactions of nitrones, including sugar nitrones, with nitroalkenes, including sugar nitroolefins, led with complete regioselectivity and stereospecificity to 4,5-trans-4-nitroisoxazolidines in 51-78% global yields. The endo/exo stereoselectivity depends on the type of sugar derivative used. As expected, the best π-diastereofacial selectivity was observed when both partners were sugar derivatives. Isomerisation of the first formed diastereomers by the action of silica gel was observed in some cases. Absolute configurations for two crystalline products were assigned by X-ray diffraction methods.