192387-14-7

Basic information

• Product Name: Benzenemethanol, 2-hydroxy-a-(2-methyl-2-propenyl)-
• CAS NO: 192387-14-7
• Molecular Formula: C11H14O2
• Molecular Weight: 178.231
• Mol File: 192387-14-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 2-hydroxy-a-(2-methyl-2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 2-hydroxy-a-(2-methyl-2-propenyl)-(192387-14-7)
• EPA Substance Registry System: Benzenemethanol, 2-hydroxy-a-(2-methyl-2-propenyl)-(192387-14-7)

Safety Data

• Hazardous Substances Data: 192387-14-7(Hazardous Substances Data)

Upstream product

• 90-02-8 salicylaldehyde 
• 563-47-3 3-Chloro-2-methylpropene 
• 89-95-2 2-methyl-benzyl alcohol 
• 5674-01-1 2-methylallylmagnesium chloride 
• 1458-98-6 2-methyl-3-bromo-1-propene 

Downstream Products

• 433955-02-3 2-[1-hydroxy-2-(2-methyl-oxiranyl)-ethyl]-phenol 

Relevant articles and documents

Carbonyl allylation of aldehydes and ketones with allylic chlorides catalyzed by immobilization of palladium in MCM-41

The heterogeneous carbonyl allylation of aldehydes and ketones with allylic chlorides was achieved in DMF using SnCl2 as reducing agent at 25-40 °C in the presence of a 3-(2-aminoethylamino)propyl-functionalized MCM-41-immobilized palladium(II) complex [MCM-41-2N-Pd(II)], yielding a variety of homoallylic alcohols in good to high yields. This heterogeneous palladium catalyst exhibited higher activity than (N-propylethylenediamine)PdCl 2 and can be recovered and recycled by a simple filtration of the reaction solution and used for at least 5 consecutive trials without any decreases in activity.

Synthesis of chromanones: A novel palladium-catalyzed Wacker-type oxidative cyclization involving 1,5-hydride alkyl to palladium migration

A series of 2-methylchromanone derivatives have been prepared by using a novel palladium-catalyzed Wacker-type oxidative cyclization, in which a 1,5-hydride alkyl to palladium migration and a direct chirality transfer were involved. The Royal Society of Chemistry.

A new and efficient synthesis of substituted 2-hydroxymethyl-2-methyl-2H-chromenes

A new and efficient three step procedure for the synthesis of functionalized 2H-chromenes 1 is described, starting from commercially available salicylaldehydes 2 and 2-methylpropenyl-magnesium chloride 3, which involves catalytic acid-mediated intramolecular cyclization of phenolic epoxide 5 as the key step.