19264-68-7

Basic information

• Product Name: 9-BENZOYLCARBAZOLE
• Synonyms: 9-BENZOYLCARBAZOLE;9-benzoyl-9h-carbazol;9-benzoyl-carbazol;(9H-carbazol-9-yl)(phenyl)Methanone;carbazol-9-yl(phenyl)methanone
• CAS NO: 19264-68-7
• Molecular Formula: C₁₉H₁₃NO
• Molecular Weight: 271.31
• EINECS: 243-031-7
• Product Categories: Carbazoles;Carbazoles (for Conduting Polymer Research);Functional Materials;Reagents for Conducting Polymer Research
• Mol File: 19264-68-7.mol
• Article Data: 29

Chemical Properties

• Melting Point: 101 °C
• Boiling Point: 391.2°Cat760mmHg
• Flash Point: 190.4°C
• Appearance: /
• Density: 1.16g/cm³
• Vapor Pressure: 1.14mmHg at 25°C
• Refractive Index: 1.499
• Solubility: soluble in Toluene
• CAS DataBase Reference: 9-BENZOYLCARBAZOLE(CAS DataBase Reference)
• NIST Chemistry Reference: 9-BENZOYLCARBAZOLE(19264-68-7)
• EPA Substance Registry System: 9-BENZOYLCARBAZOLE(19264-68-7)

Safety Data

• RTECS: FE5780000
• Hazardous Substances Data: 19264-68-7(Hazardous Substances Data)

Usage

General Description

9-BENZOYLCARBAZOLE is a chemical compound that belongs to the class of carbazole derivatives. It is a yellowish powder that is insoluble in water but soluble in organic solvents. 9-BENZOYLCARBAZOLE has been studied for its potential applications in organic electronic devices, such as organic light-emitting diodes (OLEDs) and organic photovoltaic cells (OPVs), due to its high thermal stability and good electron transporting properties. It has also been investigated for its potential antioxidant, anti-inflammatory, and neuroprotective activities. Furthermore, 9-BENZOYLCARBAZOLE has shown promise in the field of medicinal chemistry, as it exhibits anti-tumor and anti-cancer properties in certain studies. Overall, 9-BENZOYLCARBAZOLE is a versatile compound with a wide range of potential applications in various fields.

InChI:InChI=1/C5H10Br2/c1-4(6)3-5(2)7/h4-5H,3H2,1-2H3

Upstream product

• 86-74-8 9H-carbazole 
• 98-88-4 benzoyl chloride 
• 93-97-0 benzoic acid anhydride 
• 611-74-5 N,N-dimethylbenzamide 
• 769-78-8 vinyl benzoate 
• 82390-31-6 N-(2-biphenylyl)-N-hydroxybenzamide 
• 19402-87-0 9-benzyl-9H-carbazole 
• 125424-72-8 (9H-carbazol-9-yl)(2-iodophenyl)methanone 
• 21711-71-7 2-phenylnitrosobenzene 
• 16169-17-8 N-([1,1'-biphenyl]-2-yl)hydroxylamine 
• 7404-97-9 2-(benzoylamino)biphenyl 
• 591-50-4 iodobenzene 
• 13939-06-5 molybdenum hexacarbonyl 
• 15310-02-8 o-iodobenzanilide 

Downstream Products

• 19264-66-5 9H-carbazole-3-yl(phenyl)methanone 
• 177775-87-0 (3-bromo-9H-carbazol-9-yl)(phenyl)methanone 
• 912850-81-8 9-benzoyl-3,6-dibromo-carbazole 
• 101880-09-5 9-benzoyl-3-nitro-carbazole 
• 19402-87-0 9-benzyl-9H-carbazole 
• 86-74-8 9H-carbazole 
• 100-51-6 benzyl alcohol 
• 94432-46-9 C₁₉H₂₅NO 
• 93-58-3 benzoic acid methyl ester 
• 912764-83-1 1-carbazol-2-yl-2-phenyl-ethanone 
• 700863-88-3 1-(9-benzoyl-carbazol-2-yl)-2-phenyl-ethanone 
• 23592-77-0 2,9-dibenzoylcarbazole 
• 76-84-6 triphenylmethyl alcohol 
• 872270-18-3 1-(9-benzoyl-carbazol-2-yl)-ethanone 

Relevant articles and documents

Palladium-catalyzed phosphination and amination through C–H bond functionalization on biphenyl: Amido-substituent as directing group

The formation of N-(2’-(diphenylphosphoryl)-[1,1′-biphenyl]-2-yl)-2,3,4,5,6-pentafluorobenzamide (3_eaaa) has been achieved through the palladium-catalyzed and Ag(I)-assisted C–H functionalization of N-([1,1′-biphenyl]-2-yl)-2,3,4,5,6-pentafluorobenzamide

Electrochemical Palladium-Catalyzed Intramolecular C—H Amination of 2-Amidobiaryls for Synthesis of Carbazoles

The synthesis of carbazoles based on the electrochemical Pd-catalyzed intramolecular C—H amination of 2-amidobiaryls through oxidative cross coupling has been achieved under mild reaction conditions. The reaction can be carried out in undivided cell without the addition of external chemical oxidant. Besides good functional group compatibility, the desired carbazoles can be scaled up and modified easily. Compared with previous methods, this protocol affords a simple and sustainable avenue for the construction of carbazoles.

Electrochemical Synthesis of Carbazoles by Dehydrogenative Coupling Reaction

A constant current protocol, employing undivided cells, a remarkably low supporting electrolyte concentration, inexpensive electrode materials, and a straightforward precursor synthesis enabling a novel access to N-protected carbazoles by anodic N,C bond formation using directly generated amidyl radicals is reported. Scalability of the reaction is demonstrated and an easy deblocking of the benzoyl protecting group is presented.