193481-15-1

Basic information

• Product Name: Silane, [(4-bromo-2-furanyl)oxy]tris(1-methylethyl)-
• CAS NO: 193481-15-1
• Molecular Formula: C13H23BrO2Si
• Molecular Weight: 319.314
• Mol File: 193481-15-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Silane, [(4-bromo-2-furanyl)oxy]tris(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(4-bromo-2-furanyl)oxy]tris(1-methylethyl)-(193481-15-1)
• EPA Substance Registry System: Silane, [(4-bromo-2-furanyl)oxy]tris(1-methylethyl)-(193481-15-1)

Safety Data

• Hazardous Substances Data: 193481-15-1(Hazardous Substances Data)

Upstream product

• 56634-50-5 4-bromo-5H-furan-2-one 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 

Downstream Products

• 1004995-59-8 C₃₅H₅₀O₄Si₂ 
• 1004995-60-1 C₃₅H₅₀O₄Si₂ 

Relevant articles and documents

Total synthesis of (+)-dysidiolide

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Synthesis of Penta-2,4-dien-1-imines and 1,2-Dihydropyridines by Rhodium-Catalyzed Reaction of N-Sulfonyl-1,2,3-triazoles with 2-(Siloxy)furans

A rhodium(II)-catalyzed reaction of N-sulfonyl-1,2,3-triazoles with 2-(siloxy)furans is reported. Either open-chain penta-2,4-dien-1-imines or cyclic 1,2-dihydropyridines are selectively obtained depending on the ligand on rhodium(II).

2-Siloxy-4-furanyl anion: Remarkable solvent effect on its nucleophilicity

A significant solvent effect was observed for 2-triisopropylsiloxyl-4-furanyllithium complex (II) in nucleophilic addition of ketones. THF was found to be the best solvent in terms of yields and diastereoselectivity.