193560-63-3

Basic information

• Product Name: (E)-1-(N-benzyl-N-2'-carboethoxyethylamino)-1-(1-propenyl)cyclopropaneacetonitrile
• Synonyms: (E)-1-(N-benzyl-N-2'-carboethoxyethylamino)-1-(1-propenyl)cyclopropaneacetonitrile
• CAS NO: 193560-63-3
• Molecular Weight: 326.439
• Mol File: 193560-63-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-(N-benzyl-N-2'-carboethoxyethylamino)-1-(1-propenyl)cyclopropaneacetonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(N-benzyl-N-2'-carboethoxyethylamino)-1-(1-propenyl)cyclopropaneacetonitrile(193560-63-3)
• EPA Substance Registry System: (E)-1-(N-benzyl-N-2'-carboethoxyethylamino)-1-(1-propenyl)cyclopropaneacetonitrile(193560-63-3)

Safety Data

• Hazardous Substances Data: 193560-63-3(Hazardous Substances Data)

Upstream product

• 193560-61-1 1-(1-propenyl)cyclopropanecarbonitrile 
• 16529-66-1 3-Pentenenitrile 
• 7677-24-9 trimethylsilyl cyanide 
• 23583-21-3 ethyl-3-benzylamino propionate 
• 193560-62-2 1-(1-propenyl)cyclopropanecarboxaldehyde 

Relevant articles and documents

Molecular cascades. 1. Tandem cyclopropyl iminium ion rearrangement- [4+2] cycloaddition reactions

A tandem cyclopropyliminium ion rearrangement-Hofmann elimination affords rapid access to 3-vinyl Δ2-pyrrolines in some cases bearing an unsaturated tether in good yield. The resulting dienamines subsequently undergo both inter-and intramolecular [4+2] cycloaddition reactions. Good yields were obtained for a number of cases of intramolecular intermolecular cycloaddition reactions affording cycloadducts in good yields with sufficiently reactive dienophiles such as fumarate, acrylate and methacrolein. Evidence suggests a non-concerted pathway for these cycloaddition reactions.