194856-76-3

Basic information

• Product Name: 2-Octanone, 1-(phenylsulfinyl)-
• CAS NO: 194856-76-3
• Molecular Formula: C14H20O2S
• Molecular Weight: 252.378
• Mol File: 194856-76-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Octanone, 1-(phenylsulfinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Octanone, 1-(phenylsulfinyl)-(194856-76-3)
• EPA Substance Registry System: 2-Octanone, 1-(phenylsulfinyl)-(194856-76-3)

Safety Data

• Hazardous Substances Data: 194856-76-3(Hazardous Substances Data)

Upstream product

• 194856-56-9 Oct-2-ynylsulfanyl-benzene 
• 146916-28-1 <(Oct-2-ynyl)sulfinyl>benzene 
• 194856-72-9 2-diethylamino-1-octenyl phenyl sulfoxide 

Downstream Products

• 76989-79-2 1-phenylsulfinyl-octan-2-ol 
• 6169-06-8 (S)-2-Octanol 
• 5978-70-1 (R)-Octan-2-ol 

Relevant articles and documents

Synthesis of 2-acetylenic carboxylic acids, 1-sulfinyl and 1-sulfonyl- 2-ketones from 2-acetylenic phenyl sulfides

Monochlorination at the 1-position with sulfuryl chloride, followed by methanolysis converted 2-acetylenic phenyl sulfides into 1-methoxy-2- acetylenic phenyl sulfides. Oxidation with chromic acid gave 2-acetylenic carboxylic acids. Oxidation of 2-acetylenic phenyl sulfides with Oxone and hydrogen peroxide in acetic acid gave the corresponding sulfoxides and sulfones respectively. Diethylamine addition to the triple bond produced enamines which were hydrolyzed with aqueous hydrochloric acid to the corresponding 1-sulfinyl and 1-sulfonyl-2-ketones.