19487-11-7

Basic information

• Product Name: 2,6-di-tert-butyl-4-chloro-4-methylcyclohexa-2,5-dien-1-one
• Synonyms: 2,6-di-tert-butyl-4-chloro-4-methylcyclohexa-2,5-dien-1-one
• CAS NO: 19487-11-7
• Molecular Weight: 254.8
• Mol File: 19487-11-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,6-di-tert-butyl-4-chloro-4-methylcyclohexa-2,5-dien-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-di-tert-butyl-4-chloro-4-methylcyclohexa-2,5-dien-1-one(19487-11-7)
• EPA Substance Registry System: 2,6-di-tert-butyl-4-chloro-4-methylcyclohexa-2,5-dien-1-one(19487-11-7)

Safety Data

• Hazardous Substances Data: 19487-11-7(Hazardous Substances Data)

Upstream product

• 128-37-0 2,6-di-tert-butyl-4-methyl-phenol 
• 130-15-4 [1,4]naphthoquinone 

Downstream Products

• 51033-92-2 bis(1-methyl-3,5-di-tert-butyl-4-oxo-cyclohexa-2,5-dienyl) peroxide 
• 1219595-77-3 2,6-di-tert-butyl-4-isopropoxy-4-methylcyclohexa-2,5-dienone 
• 38876-35-6 2,6-di-tert-butyl-4-ethoxy-4-methylcyclohexa-2,5-dienone 
• 87-97-8 2,6-di-tert-butyl-4-methoxymethylene-phenol 
• 2411-18-9 4-methoxy-4-methyl-2,6-ditert-butylcyclohexa-2,5-dienone 
• 10396-80-2 2,6-di-tert-butyl-4-hydroxy-4-methylcyclohexa-2,5-dienone 

Relevant articles and documents

Electrochemical chlorination and bromination of electron-deficient C[sbnd]H bonds in quinones, coumarins, quinoxalines and 1,3-diketones

The electrochemistry-promoted chlorination and bromination of electron-deficient C[sbnd]H bonds was developed, using quinones, coumarins, quinoxalines and 1,3-diketones. This protocol features readily available and safe halogen sources (hydrochloric acid and KBr), high site-selectivity and mild reaction conditions. It could provide an efficient access to a series of chlorinated and brominated quinones, coumarins, quinoxalines and 1,3-diketones.

The Chlorination of 2-t-Butyl-4,6-dimethylphenol and 2,6-Di-t-butyl-4-methylphenyl. The Formation of 5,6-Dichloro-4-methylenecyclohex-2-enones

The chlorination in acetic acid of 2-t-butyl-4,6-dimethylphenyl (1) gives two chloromethylene compounds (4) and (5), and trichloro ketones (6) and (7).In contrast, 2,6-di-t-butyl-4-methylphenol (2) gives six chlorination products (14)-(19).The notable fea