195006-97-4

Basic information

• Product Name: dodecyl 2-amino-(R)-4,6-O-benzylidene-2-deoxy-β-D-allopyranoside
• Synonyms: dodecyl 2-amino-(R)-4,6-O-benzylidene-2-deoxy-β-D-allopyranoside
• CAS NO: 195006-97-4
• Molecular Weight: 435.604
• Mol File: 195006-97-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: dodecyl 2-amino-(R)-4,6-O-benzylidene-2-deoxy-β-D-allopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: dodecyl 2-amino-(R)-4,6-O-benzylidene-2-deoxy-β-D-allopyranoside(195006-97-4)
• EPA Substance Registry System: dodecyl 2-amino-(R)-4,6-O-benzylidene-2-deoxy-β-D-allopyranoside(195006-97-4)

Safety Data

• Hazardous Substances Data: 195006-97-4(Hazardous Substances Data)

Upstream product

• 112-53-8 1-dodecyl alcohol 
• 3068-34-6 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-chloro-tetrahydro-pyran-4-yl ester 
• 211567-26-9 Methanesulfonic acid (2R,4aR,6R,7R,8R,8aR)-7-acetylamino-6-dodecyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester 
• 211567-22-5 dodecyl 3,4,6-tri-O-acetyl-2-(acetylamino)-2-deoxy-β-D-glucopyranoside 
• 147025-06-7 dodecyl 2-(acetylamino)-2-deoxy-β-D-glucopyranoside 
• 154564-64-4 dodecyl 2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside 
• 100-52-7 benzaldehyde 
• 434948-95-5 1-dodecyl (R)-4,6-O-benzylidene-2-deoxy-2-(trans-3-phenyl-2-propenamido)-β-D-allopyranoside 
• 434949-32-3 1-dodecyl 2-amino-(R)-4,6-O-benzylidene-2-deoxy-2-N-3-O-methylidene-2-N-(trans-3-phenyl-2-propenoyl)-β-D-allopyranoside 
• 434949-67-4 1-dodecyl 2-amino-(R)-4,6-O-benzylidene-2-deoxy-2-N-[(2S,3R)-2,3-epoxy-3-phenylpropanoyl]-2-N-3-O-methylidene-β-D-allopyranoside 
• 211567-29-2 1-dodecyl 2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-allopyranoside 

Downstream Products

• 434948-95-5 1-dodecyl (R)-4,6-O-benzylidene-2-deoxy-2-(trans-3-phenyl-2-propenamido)-β-D-allopyranoside 
• 434949-67-4 1-dodecyl 2-amino-(R)-4,6-O-benzylidene-2-deoxy-2-N-[(2S,3R)-2,3-epoxy-3-phenylpropanoyl]-2-N-3-O-methylidene-β-D-allopyranoside 
• 434949-32-3 1-dodecyl 2-amino-(R)-4,6-O-benzylidene-2-deoxy-2-N-3-O-methylidene-2-N-(trans-3-phenyl-2-propenoyl)-β-D-allopyranoside 
• 211567-35-0 Bis-(2-chloro-ethyl)-((3aR,4R,5aR,8R,9aR,9bS)-4-dodecyloxy-2-oxo-8-phenyl-octahydro-1,5,7,9-tetraoxa-3-aza-2λ⁵-phospha-cyclopenta[a]naphthalen-2-yl)-amine 

Relevant articles and documents

Stereoselective synthesis of oxiranes using oxazolidines derived from 2-amino-2-deoxy-D-allose as chiral auxiliaries

The synthesis of 2,3-epoxyamide derivatives of 2-amino-2-deoxy-D-allose is described. Epoxidation of the corresponding α,β-unsaturated amides with m-CPBA took place with better stereoselectivity when an oxazolidine ring was fused to the 2,3-positions of the sugar molecule. In most cases, both stereoisomers could be isolated and characterized. The stereochemistry of the new stereogenic centers was then determined by cleavage of the oxirane moiety from the chiral auxiliary, which was also recovered.