195135-61-6

Basic information

• Product Name: [Cu(NO₂NCN)(P(C₆H₅)3)2]2
• CAS NO: 195135-61-6
• Molecular Weight: 1348.32
• Mol File: 195135-61-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Cu(NO₂NCN)(P(C₆H₅)3)2]2(CAS DataBase Reference)
• NIST Chemistry Reference: [Cu(NO₂NCN)(P(C₆H₅)3)2]2(195135-61-6)
• EPA Substance Registry System: [Cu(NO₂NCN)(P(C₆H₅)3)2]2(195135-61-6)

Safety Data

• Hazardous Substances Data: 195135-61-6(Hazardous Substances Data)

Upstream product

• 78991-01-2 potassium cyanamidonitrate 

Relevant articles and documents

Pseudoelement compounds. XI. [1]: Investigations on the coordination behaviour of cyanamidonitrate [NO2NCN]-

With the ionic, potentially ambidentate ligand cyanamidonitrate complexes of the types [MX(PPh3)3], [MX(PPh3)2]2 (M = CuI, AgI) and trans-[Pt(H)X(PPh3)2] (X- = [NO2NCN]-) are introduced. The new compounds are characterized by 1H NMR, 31P NMR, and IR spectroscopy. The crystal structures of [Cu(NO2NCN)(PPh3)2]2 and [Ag(NO2NCN)(PPh3)2]2 are reported. In the complexes [MX(PPh3)3] and trans-[Pt(H)X(PPh3)2] cyanamidonitrate is unidentately coordinated through the nitrile group end-on In the dimeric complexes [MX(PPh3)2]2 the anion acts bidentately as a bridging ligand. Surprisingly, both coordinative bonds are formed through nitrogen atoms of the NCN group.