1959-48-4

Basic information

• Product Name: Benzene, 1,1'-(bromofluoroethenylidene)bis-
• CAS NO: 1959-48-4
• Molecular Formula: C14H10BrF
• Molecular Weight: 277.136
• Mol File: 1959-48-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(bromofluoroethenylidene)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(bromofluoroethenylidene)bis-(1959-48-4)
• EPA Substance Registry System: Benzene, 1,1'-(bromofluoroethenylidene)bis-(1959-48-4)

Safety Data

• Hazardous Substances Data: 1959-48-4(Hazardous Substances Data)

Upstream product

• 1868-53-7 dibromofluoromethane 
• 908093-98-1 diazodiphenylmethane 
• 15052-21-8 2-fluoro-3,3-diphenylprop-2-enoic acid 
• 119-61-9 benzophenone 
• 42117-07-7 ethyl 2-fluoro-3,3-diphenylprop-2-enoate 
• 353-54-8 tribromofluoromethane 
• 390-75-0 2-fluoro-1,1-diphenylethene 

Downstream Products

• 390-75-0 2-fluoro-1,1-diphenylethene 

Relevant articles and documents

PHOTOCHEMISTRY OF ORGANOHALOGENO-COMPOUNDS. PART XIX THE EFFECT OF FLUORINE ON PHOTOCHEMICAL CARBON-HALOGEN BOND CLEAVAGE

Irradiation of 1,1-diphenyl-2-fluoro-2-haloethenes at λ = 253.7 nm gave 1,1-diphenyl-2-fluoroethene and the rearranged product trans-fluorostilbene.The phototransformation depended on the halogen present and the solvent used.Introduction of fluorine on th

Low-temperature 19F NMR spectroscopy of 1-fluoro-1-lithioethenes - Stability, shifts and unexpected coupling constants

Half-lives and fluorine atom shifts of stabilized 1-fluoro-l-lithioethenes bearing hydrogen, fluorine, phenyl, and/or dimethylphenylsilyl groups in the β-positions have been determined by a low-temperature 19F NMR spectroscopy. Some 1-fluoro-1-lithioethenes displayed an exceptionally low value of the trans-3JFF coupling constant. Stereoselectivity of carbenoid formation, as well as an effect of configuration on the stability is discussed.