196191-22-7

Basic information

• Product Name: N-Benzyl-2-(2-bromophenyl)-N-(2,2-bis(phenylsulfanyl)ethenyl)acetamide
• CAS NO: 196191-22-7
• Molecular Weight: 546.552
• Mol File: 196191-22-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-Benzyl-2-(2-bromophenyl)-N-(2,2-bis(phenylsulfanyl)ethenyl)acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-Benzyl-2-(2-bromophenyl)-N-(2,2-bis(phenylsulfanyl)ethenyl)acetamide(196191-22-7)
• EPA Substance Registry System: N-Benzyl-2-(2-bromophenyl)-N-(2,2-bis(phenylsulfanyl)ethenyl)acetamide(196191-22-7)

Safety Data

• Hazardous Substances Data: 196191-22-7(Hazardous Substances Data)

Upstream product

• 100-46-9 benzylamine 
• 153823-24-6 Bis(phenylsulfanyl)acetaldehyde 
• 55116-09-1 2-bromophenylacetyl chloride 
• 1026402-78-7 Benzyl-(2,2-bis-phenylsulfanyl-vinyl)-amine 

Relevant articles and documents

Sulfur-controlled 6-exo aryl radical cyclisation of N-ethenyl-2-(2-bromophenyl)acetamides: Synthesis of (±)-tetrahydropalmatine and saulatine

Bu3SnH-mediated aryl radical cyclisation of 2-(2-bromophenyl)-N-[2,2-bis(phenylsulfanyl)ethenyl]-acetamide 7 takes place in a 6-exo-trig manner to give the isoquinolinone 9. The method has been applied to the synthesis of (±)-tetrahydropalmatine 16 and saulatine 24.