197291-57-9

Basic information

• Product Name: Acrylic acid (4S,5S)-2-(2-methylsulfanyl-phenyl)-5-phenyl-4,5-dihydro-oxazol-4-ylmethyl ester
• Synonyms: Acrylic acid (4S,5S)-2-(2-methylsulfanyl-phenyl)-5-phenyl-4,5-dihydro-oxazol-4-ylmethyl ester
• CAS NO: 197291-57-9
• Molecular Weight: 353.442
• Mol File: 197291-57-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acrylic acid (4S,5S)-2-(2-methylsulfanyl-phenyl)-5-phenyl-4,5-dihydro-oxazol-4-ylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acrylic acid (4S,5S)-2-(2-methylsulfanyl-phenyl)-5-phenyl-4,5-dihydro-oxazol-4-ylmethyl ester(197291-57-9)
• EPA Substance Registry System: Acrylic acid (4S,5S)-2-(2-methylsulfanyl-phenyl)-5-phenyl-4,5-dihydro-oxazol-4-ylmethyl ester(197291-57-9)

Safety Data

• Hazardous Substances Data: 197291-57-9(Hazardous Substances Data)

Upstream product

• 28143-91-1 (1S,2S)-2-amino-1-phenyl-1,3-diol 
• 6609-54-7 2-cyanothioanisole 
• 814-68-6 acryloyl chloride 
• 160246-26-4 [(4S,5S)-2-(2-Methylsulfanyl-phenyl)-5-phenyl-4,5-dihydro-oxazol-4-yl]-methanol 

Downstream Products

• 159991-80-7 endo-benzyl bicyclo[2.2.1]hept-5-ene-2-carboxylate 

Relevant articles and documents

Auxiliary accelerated reactions: Towards the use of catalytic chiral auxiliaries

In competition experiments, the acceleration of reactivity of alkenes tethered to pyridyl groups compared with the corresponding alkenes tethered to phenyl groups in the presence of transition metals was demonstrated for two reaction types: Diels-Alder cycloaddition of enoate esters and catalytic hydrogenation of allylic and homoallylic ethers. The rate accelerations observed are of crucial importance in the development of a new concept for asymmetric catalysis: chiral auxiliaries which can function in a catalytic manner.