19769-32-5

Basic information

• Product Name: 6-(methylsulfonyl)-5H-purine
• CAS NO: 19769-32-5
• Molecular Formula: C₆H₆N₄O₂S
• Molecular Weight: 198.2024
• Mol File: 19769-32-5.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 364.5°C at 760 mmHg
• Flash Point: 174.2°C
• Density: 1.79g/cm³
• Vapor Pressure: 3.52E-05mmHg at 25°C
• Refractive Index: 1.792
• CAS DataBase Reference: 6-(methylsulfonyl)-5H-purine(CAS DataBase Reference)
• NIST Chemistry Reference: 6-(methylsulfonyl)-5H-purine(19769-32-5)
• EPA Substance Registry System: 6-(methylsulfonyl)-5H-purine(19769-32-5)

Safety Data

• Hazardous Substances Data: 19769-32-5(Hazardous Substances Data)

Upstream product

• 157930-09-1 6-Mercaptopurine 
• 50-66-8 6-methylthiopurine 
• 67-56-1 methanol 
• 7732-18-5 water 
• 7782-50-5 chlorine 
• 50-66-8 6-(methylthio)-1H-purine 

Downstream Products

• 1928-89-8 4-(pyrrolidin-1-yl)-7H-pyrrolo[2,3-d]pyrimidine 
• 525-79-1 kinetin 
• 2312-73-4 6-benzylamino-9-(2-tetrahydropyranyl)purine 
• 109403-64-7 6-furfurylamino-9-(tetrahydropyran-2-yl)-9H-purine 
• 84602-83-5 N-phenyl-9-(tetrahydro-2H-pyran-2-yl)-9H-purin-6-amine 
• 1214-39-7 6-benzyladenine 
• 1210-66-8 N-phenyl-9H-purin-6-amine 
• 5451-41-2 N⁶-butyladenine 

Relevant articles and documents

Metal-Free Aminomethylation of Aromatic Sulfones Promoted by Eosin Y

A metal-free α-aminomethylation of heteroaryls promoted by eosin Y under green light irradiation is reported. A large variety of α-trimethylsilylamines as precursor of α-aminomethyl radical species were engaged to functionalize sulfonyl-heteroaryls following a Homolytic Aromatic Substitution (HAS) pathway. This method has provided a range of α-aminoheteroaryl compounds including a functionalized natural product. The mechanism of this late-stage functionalization of aryls was investigated and suggests the formation of a sulfonyl radical intermediate over a reductive quenching cycle.