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19813-76-4

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19813-76-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 19813-76-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,9,8,1 and 3 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 19813-76:
(7*1)+(6*9)+(5*8)+(4*1)+(3*3)+(2*7)+(1*6)=134
134 % 10 = 4
So 19813-76-4 is a valid CAS Registry Number.

19813-76-4Relevant articles and documents

Cobalt-catalyzed C(sp2)?CN bond activation: Cross-electrophile coupling for biaryl formation and mechanistic insight

Dorval, Céline,Tricoire, Maxime,Begouin, Jeanne-Marie,Gandon, Vincent,Gosmini, Corinne

, p. 12819 - 12827 (2020/11/18)

Herein, we report a cross-electrophile coupling of benzonitrile derivatives and aryl halides with a simple cobalt-based catalytic system under mild conditions to form biaryl compounds. Even though the cobalt catalyst is able to activate the C(sp2)?CN bond alone, the use of the AlMe3 Lewis acid enhances the reactivity of benzonitriles and improves the cross-selectivity with barely any influence on the functional group compatibility. X-ray structure determination of an original low-valent cobalt species combined with catalytic and stoichiometric reactions reveals a catalytically active cobalt(I) species toward the aryl halide partner. On the other hand, experimental insights, including cyclic voltammetry experiments, suggest the involvement of a cobalt complex of a lower oxidation state to activate the benzonitrile derivative. Finally, density functional theory calculations support the proposed mechanistic cycle involving two low-valent cobalt species of different oxidation states to perform the reaction.

Photochemical arylation reactions by 4-chlorothioanisole

Lazzaroni, Simone,Dondi, Daniele,Fagnoni, Maurizio,Albini, Angelo

, p. 4360 - 4365 (2008/04/13)

The photochemistry of 4-chlorothioanisole (1) was investigated in various solvents, and it was found to involve the reduction to thioanisole as the main process. This occurs by heterolytic fragmentation of the triplet state of 1 and formation of the triplet 4-thiomethoxyphenylium ion, as supported by DFT calculations. The cation is trapped by alkenes and, less efficiently, by benzene, resulting in new examples of the recently emerging arylation reactions by SN1 substitution of phenyl halides. The products from alkenes involve the phenonium ion as a further intermediate. The product distribution differs from the analogous reactions via 4-methoxyphenylium for including a larger proportion of 4-(β-substituted alkyl)- rather than 4-allylthioanisoles derivatives in alcohols, for the lower fraction of rearranged α-substituted 4-alkyl-thioanisoles and for the formation of some 4-cyclopropylthioanisole with allyltrimethylsilane. The difference is accounted for by the more developed dipolar character of the C-C cyclopropane bonds in the intermediate phenonium, as indicated by DFT calculations. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.

Photoinduced nucleophilic substitution of aryl halides with potassium thioacetate - A one-pot approach to aryl methyl and diaryl sulfides

Schmidt, Luciana C.,Rey, Valentina,Penenory, Alicia B.

, p. 2210 - 2214 (2007/10/03)

Aryl methyl sulfides and diaryl sulfides were prepared by photoinduced reactions of potassium thioacetate with aryl halides under entrainment conditions. Without isolation, the arene thiolates obtained by the aromatic substitution were quenched with methyl iodide to afford the aryl methyl sulfides in 26-59% yields in a "one-pot" procedure together with the diaryl sulfides in variable yields (3-31 %). By optimization of the reaction conditions it was possible to improve the formation of the Ar2S, going from moderate to good yields (64-83%). Wiley-VCH Verlag GmbH & Co. KGaA, 2006.

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