199122-70-8

Basic information

• Product Name: (1S,4R,5R,6S)-5-[(R)-((1R,2S)-2-Benzyloxy-cyclooctyloxy)-methoxy-methyl]-6-methyl-bicyclo[2.2.1]hept-2-ene
• Synonyms: (1S,4R,5R,6S)-5-[(R)-((1R,2S)-2-Benzyloxy-cyclooctyloxy)-methoxy-methyl]-6-methyl-bicyclo[2.2.1]hept-2-ene
• CAS NO: 199122-70-8
• Molecular Weight: 384.559
• Mol File: 199122-70-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1S,4R,5R,6S)-5-[(R)-((1R,2S)-2-Benzyloxy-cyclooctyloxy)-methoxy-methyl]-6-methyl-bicyclo[2.2.1]hept-2-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,4R,5R,6S)-5-[(R)-((1R,2S)-2-Benzyloxy-cyclooctyloxy)-methoxy-methyl]-6-methyl-bicyclo[2.2.1]hept-2-ene(199122-70-8)
• EPA Substance Registry System: (1S,4R,5R,6S)-5-[(R)-((1R,2S)-2-Benzyloxy-cyclooctyloxy)-methoxy-methyl]-6-methyl-bicyclo[2.2.1]hept-2-ene(199122-70-8)

Safety Data

• Hazardous Substances Data: 199122-70-8(Hazardous Substances Data)

Upstream product

• 90719-37-2 (4S,1'R,2'R,3'S,4'S)-3-[(3'-methylbicyclo[2.2.1]hept-5'-ene-2'-yl)carbonyl]-4-iso-propyloxazolidin-2-one 
• 199122-21-9 (2S,3aS,9aR)-2-((1R,2R,3S,4S)-3-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-octahydro-cycloocta[1,3]dioxole 
• 199122-29-7 C₁₈H₂₉BrO₃ 
• 94668-49-2 (1R,2R,3S,4S)-3-methyl-5-norbornene-2-methanol 
• 153380-53-1 (1R,2R,3S,4S)-3-methylbicyclo[2.2.1]hept-5-en-2-carboxaldehyde 
• 27607-33-6 (1R,2S)-Cyclooctane-1,2-diol 
• 100-39-0 benzyl bromide 
• 199122-50-4 (1S,2R)-2-[(R)-Methoxy-((1R,2R,3S,4S)-3-methyl-bicyclo[2.2.1]hept-5-en-2-yl)-methoxy]-cyclooctanol 

Downstream Products

• 199122-21-9 (2S,3aS,9aR)-2-((1R,2R,3S,4S)-3-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-octahydro-cycloocta[1,3]dioxole 

Relevant articles and documents

Asymmetric desymmetrization of saturated and unsaturated meso-1,2-diols

An asymmetric desymmetrization of saturated and unsaturated cyclic and acyclic meso-1,2-diols has been developed from the ene acetals, prepared from the norbornene carboxyaldehyde and meso-1,2-diols. The intramolecular haloetherification of the ene acetals as a key step afforded 8-membered acetals in a stereoselective manner just by the reaction of norbornene olefin even when the ene acetals from unsaturated meso-1,2-diols having olefins in the same molecule were used. Subsequent reductive elimination, followed by protecting the hydroxy group and transacetalization, gave optically active 1,2-diol derivatives and the starting ene acetals in good yields. (C) 2000 Elsevier Science Ltd.