19926-49-9Relevant articles and documents
Synthesis, characterization and computational evaluation of bicyclooctadienes towards molecular solar thermal energy storage
Erdelyi, Mate,Ghasemi, Shima,Hillers-Bendtsen, Andreas Erbs,Kann, Nina,Mikkelsen, Kurt V.,Moth-Poulsen, Kasper,Muhammad, Lidiya M.,Quant, Maria,Wang, Zhihang
, p. 834 - 841 (2022/02/07)
Molecular solar-thermal energy storage (MOST) systems are based on photoswitches that reversibly convert solar energy into chemical energy. In this context, bicyclooctadienes (BODs) undergo a photoinduced transformation to the corresponding higher energy
Regioselective synthesis of substituted cyclohexa-1,3-dienes via the base-mediated cyclisation of α,β-unsaturated carbonyl compounds and γ-phosphonylcrotonates
Chandra, Rajesh,Joshi, Prabhakar R.,Menon, Rajeev S.
, (2020/09/04)
The base-mediated reaction of α,β-unsaturated carbonyl compounds and γ-phosphonylcrotonates under an argon atmosphere readily furnishes substituted cyclohexa-1,3-dienes. The cyclisation proceeds with complete regioselectivity to afford products that are r
Base-free Pd-MOF catalyzed the Suzuki-Miyaura cross-coupling reaction of arenediazonium tetrafluoroborate salts with arylboronic acids
Liu, Yangyang,Wang, Jie,Li, Tang,Zhao, Zesheng,Pang, Wan
, (2019/09/10)
A convenient and environmental benign synthesis of biaryls has been demonstrated by a straightforward reaction catalyzed by the palladium-containing metal-organic framework (Pd-MOF) [Pd (2-pymo)2]n (2-pymo = 2-pyrimidinolate). A series of functionalized biaryl derivatives have been synthesized in good to excellent yields by the Suzuki-miyaura cross-couplings of sustainable arenediazonium salts with a variety of arylboronic acids and the reactions were catalyzed by the Pd-MOF using methanol as a benign solvent. Those base- and additive-free catalytic reactions proceeded smoothly under non-anhydrous and non-degassed condition. Such transformation avoided high reaction temperature, tolerated many functional groups and presented a wide substrate scope. The catalyst could be recovered by filtration and reused for four successive cycles before collapse of the MOF structure.