19936-85-7

Basic information

• Product Name: Benzenemethanol, 2,3,4,5,6-pentamethyl-, acetate
• Synonyms: 2,3,4,5,6-pentamethylbenzyl acetate;acetic acid pentamethylphenylmethyl ester;1-acetoxymethyl-2,3,4,5,6-pentamethylbenzene;Pentamethylbenzylacetate;Benzenemethanol,2,3,4,5,6-pentamethyl-,acetate
• CAS NO: 19936-85-7
• Molecular Formula: C14H20O2
• Molecular Weight: 220.312
• Mol File: 19936-85-7.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 2,3,4,5,6-pentamethyl-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 2,3,4,5,6-pentamethyl-, acetate(19936-85-7)
• EPA Substance Registry System: Benzenemethanol, 2,3,4,5,6-pentamethyl-, acetate(19936-85-7)

Safety Data

• Hazardous Substances Data: 19936-85-7(Hazardous Substances Data)

Upstream product

• 4382-76-7 methoxymethyl acetate 
• 700-12-9 pentamethylbenzene, 
• 484-65-1 2,3,4,5,6-pentamethylbenzyl chloride 
• 64-19-7 acetic acid 
• 87-85-4 Hexamethylbenzene 
• 127-09-3 sodium acetate 
• 53442-65-2 2,3,4,5,6,-pentamethylbenzyl bromide 

Downstream Products

• 484-66-2 2,3,4,5,6-pentamethylbenzyl alcohol 
• 64489-86-7 N-Pentamethylbenzyl-n-nonanamid 
• 21979-72-6 Bis-(pentamethylbenzyl)-durol 

Relevant articles and documents

Negative-working photosensitive poly(phenylene ether) based on poly(2,6-dimethyl-1,4-phenylene ether), a cross-linker, and a photoacid generator

A novel benzyl cation type cross-linker, hex-1,6-ylenebis[oxy(2,4,6- tris(acetyloxymethyl)-3,5-dimethylbenzene)] (HOAD), that suppresses acid-catalyzed self-polycondensation has been developed. Furthermore, a negative-working, photosensitive poly(phenylen

Effective and versatile functionalisation of hexamethylbenzene using N-F reagents

Effective direct introduction of alkoxy, amido, azido or halogeno functional groups on the benzylic position in hexamethyl-benzene was mediated by the N-F reagents F-TEDA-BF4, NFTh, NFSi or FP-B800 in the presence of alcohols, carboxylic acids, cyanides or trimethylsilyl derivatives as sources of an external nucleophile.

OXIDATION OF HEXAMETHYLBENZENE AND 2,3,4,5,6-PENTAMETHYLBENZYL CATION IN FLUOROSULFONIC ACID

The oxidation of hexamethylbenzene in HSO3F-PbO2 takes place with the participation of the 1-H+-1,2,3,4,5,6-hexamethylbenzenonium ion and the intermediate formation of the 2,3,4,5,6-pentamethylbenzyl cation, which is capable of entering into further oxidative transformations leading to substitution of the hydrogen atom in two and three methyl groups.The structure of the final products from the observed transformations were established, and a mechanism is proposed for their formation.