199541-16-7

Basic information

• Product Name: [RuCl(S-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine))(benzene)]Cl
• CAS NO: 199541-16-7
• Molecular Weight: 832.708
• Mol File: 199541-16-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [RuCl(S-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine))(benzene)]Cl(CAS DataBase Reference)
• NIST Chemistry Reference: [RuCl(S-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine))(benzene)]Cl(199541-16-7)
• EPA Substance Registry System: [RuCl(S-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine))(benzene)]Cl(199541-16-7)

Safety Data

• Hazardous Substances Data: 199541-16-7(Hazardous Substances Data)

Upstream product

• 133545-16-1 (S)-(-)-2,2'-bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl 
• 37366-09-9 (η(6)-benzene)dichlororuthenium dimer 

Relevant articles and documents

Binap and MeO-Biphep complexes of Ru(II). Dicationic ligands as 6e donors. Unexpected cyclometallation in connection with P - C bond breaking

A series of cationic and dicationic Ru-arene complexes with Binap (1a) and MeO-Biphep (1b) have been prepared. 13C NMR studies are shown to be useful in connection with recognising the 6e-bonding mode of 1a and 1b in the dications [Ru(1a or 1b)(η6-arene)](SbF6)2 (8, 9). Reaction of 8, 9 with: (a) (Bu4N)(Ph3SiF2) leads to a cyclometallated product which arises via P - C bond breaking and P - F bond making; (b) methanol provides a straightforward synthesis of the corresponding hydrides. 13C NMR p-cymene chemical shifts are reported.