19980-19-9

Basic information

• Product Name: Silane, [[4-(1,1-dimethylethyl)-1-cyclohexen-1-yl]oxy]trimethyl-
• CAS NO: 19980-19-9
• Molecular Formula: C13H26OSi
• Molecular Weight: 226.434
• Mol File: 19980-19-9.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Silane, [[4-(1,1-dimethylethyl)-1-cyclohexen-1-yl]oxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [[4-(1,1-dimethylethyl)-1-cyclohexen-1-yl]oxy]trimethyl-(19980-19-9)
• EPA Substance Registry System: Silane, [[4-(1,1-dimethylethyl)-1-cyclohexen-1-yl]oxy]trimethyl-(19980-19-9)

Safety Data

• Hazardous Substances Data: 19980-19-9(Hazardous Substances Data)

Upstream product

• 31469-15-5 1-methoxy-2-methyl-1-trimethylsiloxy-1-propene 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 937-07-5 4-tert-butylcyclohex-2-enone 
• 115262-00-5 [chloro(difluoro)methyl]trimethylsilane 
• 18156-74-6 1-(Trimethylsilyl)imidazole 
• 13435-12-6 N-Trimethylsilylacetamide 
• 762-72-1 allyl-trimethyl-silane 
• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 16029-98-4 trimethylsilyl iodide 

Downstream Products

• 59454-26-1 (4-tert-Butyl-bicyclo[4.1.0]hept-1-yloxy)-trimethyl-silane 
• 1544-02-1 trans 2-fluoro-4-tert-butyl cyclohexanone 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 35376-40-0 trans 4-tert-butylcyclohexen-1-ol 
• 35376-39-7 cis 4-tert-butylcyclohexen-1-ol 
• 3211-27-6 4-tert-butyl-2-methylcyclohexanone 
• 3211-27-6 4-tert-butyl-2-methylcyclohexanone 
• 5064-52-8 2-methyl-4-tert-butylcyclohexanone 
• 60774-46-1 4-tert-butyl-2-phenylsulfanylcyclohexanone 
• 128920-96-7 trans-4-tert-butyl-2-(3-oxobutyl)cyclohexanone 

Relevant articles and documents

Easy preparation of enoxysilanes from aldehydes and ketones catalyzed by samarium diiodide

Ketones and α-substituted aldehydes are converted to trimethylsilyl enol ethers by reaction with the trimethylsilyl ketene acetal of methyl isobutyrate in dichloromethane in presence of a catalytic amount of samarium diiodide.

Halogenative difluorohomologation of ketones

A method for the difluorohomologation of ketones accompanied by halogenation of a C-H bond is described. The reaction involves silylation, difluorocarbene addition using Me3SiCF2Br activated by a bromide ion, and halogenation of intermediate cyclopropanes with N-bromo- or N-iodosuccinimide. The whole process is performed without isolation of intermediates. The resulting α,α-difluoro-β-halo-substituted ketones can be readily converted into fluorine containing pyrazole derivatives and oxetanes.

METHOD FOR PRODUCING SILYLENOL ETHERS

The present invention provides a method for producing a silyl enol ether compound, which is convenient, has highly broad utility and places a low environmental load (less waste). The present invention relates to a method for producing silyl enol ether compound (3), including reacting ketone or aldehyde compound (1) with allylsilane compound (2) in the presence of a base and 0.00001 to 0.5 equivalents of an acid catalyst relative to ketone or aldehyde compound (1), wherein R1 is a hydrogen atom, an alkyl group, an aryl group or the like; R2 and R3 are each a hydrogen atom, a halogen atom, an alkyl group, an aryl group or the like; R1 and R3, R1 and R2, or R2 and R3 optionally form a ring, together with the carbon atom(s) bonded thereto; R4 , R5 and R6 are each a hydrogen atom, an alkyl group or the like; two of R4, R5 and R6 optionally form a ring; R7, R8, R9, R10 and R11 are each a hydrogen atom, an alkyl group or the like; two of R7, R8, R9, R10 and R11 optionally form a ring.