20024-90-2Relevant articles and documents
Enantio- and regioselective intermolecular benzylic and allylic C-H bond amination
Nishioka, Yota,Uchida, Tatsuya,Katsuki, Tsutomu
supporting information, p. 1739 - 1742 (2013/04/23)
Smooth salen: Ru(CO)-salen complex 1 is an effective catalyst for asymmetric benzylic and allylic C-H bond amination using 2-(trimethylsilyl) ethanesulfonyl azide (SESN3) as the nitrene source. The reaction proceeded with high enantioselectivity and excellent regioselectivity. An ethyl group can be selectively aminated, even in the presence of an n-propyl group. No migration or isomerization of the double bond was observed. Copyright