20052-58-8Relevant articles and documents
REGIOSPECIFIC ALKENYLATION OF PHENOLS BY 1,1-DIMETHYLALLENE PROMOTED BY PLATINUM CATALYSTS
Renzi, Augusto De,Panunzi, Achille,Saporito, Antonio,Vitagliano, Aldo
, p. 993 - 996 (2007/10/02)
1,1-Dimethylallene reacts with phenolic substrates in the presence of catalytic amounts of platinum(II) complexes.A regiospecific C-alkenylation takes place, affording o-isopentenylphenols and 2,2-dimethylchromans.Possible reaction mechanisms are also discussed.