202831-66-1

Basic information

• Product Name: 6-bromo-N-phenylnaphthalene-2-amine
• Synonyms: 6-bromo-N-phenylnaphthalene-2-amine
• CAS NO: 202831-66-1
• Molecular Weight: 298.182
• Mol File: 202831-66-1.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 6-bromo-N-phenylnaphthalene-2-amine(CAS DataBase Reference)
• NIST Chemistry Reference: 6-bromo-N-phenylnaphthalene-2-amine(202831-66-1)
• EPA Substance Registry System: 6-bromo-N-phenylnaphthalene-2-amine(202831-66-1)

Safety Data

• Hazardous Substances Data: 202831-66-1(Hazardous Substances Data)

Upstream product

• 5111-65-9 2-Bromo-6-methoxynaphthalene 
• 62-53-3 aniline 
• 15231-91-1 6-bromo-naphthalen-2-ol 
• 6192-52-5 p-toluenesulfonic acid monohydrate 

Downstream Products

• 1310875-35-4 6-(phenylamino)naphthalene-2-phosphonic acid 
• 1310875-36-5 6-(phenylamino)naphthalen-2-ylphosphonic dichloride 
• 1310906-22-9 C₅₅H₅₀NO₉P 
• 1310875-26-3 C₅₅H₅₀NO₉P 
• 1310875-34-3 diethyl 6-(phenylamino)naphthalene-2-phosphonate 
• 60706-24-3 [Zn(mthd)₂(bpy)] 
• 1239605-45-8 trimethyl(6-phenylnaphthalen-2-yl)silane 
• 1622884-28-9 N,N-diphenyl-6-vinylnaphthalen-2-amine 
• 6410-02-2 N,N'-Diphenyl-2,6-naphthylenediamine 
• 1404196-54-8 (E)-2-cyano-3-(4-((E)-2-(6-(diphenylamino)naphthalen-2-yl)vinyl)phenyl)acrylic acid 
• 1404196-32-2 (E)-4-(2-(6-(diphenylamino)naphthalen-2-yl)vinyl)benzaldehyde 
• 1404196-29-7 (E)-6-(4-bromostyryl)-N,N-diphenylnaphthalen-2-amine 
• 1283147-67-0 N₂,N₂-bis(2-(diphenylamino)naphthalen-6-yl)-N₆,N₆-dipheylnaphthalene-2,6-diamine 

Relevant articles and documents

Organic micromolecular material with high refractive index and application thereof

The invention belongs to the technical field of organic photoelectric materials, and discloses an organic micromolecular material with a high refractive index and application thereof. The structure of the organic micromolecular material with a high refrac

Nucleophilic ipso-Substitution of Aryl Methyl Ethers through Aryl C-OMe Bond Cleavage; Access to Functionalized Bisthiophenes

A metal and solvent free strategy to functionalize aryl methyl ethers through direct nucleophilic substitution of aryl C-OMe bond has been described. A wide range of O, S, N, and C-centered uncharged nucleophiles has been successfully employed. Using this protocol, functional derivatives of bisthiophene have been synthesized in a straightforward way. The reactions are highly atom-efficient and generate methanol as the only byproduct.

Structure-property relationship of naphthalene based donor-π-acceptor organic dyes for dye-sensitized solar cells: Remarkable improvement of open-circuit photovoltage

Four new donor-π-acceptor organic dyes (YF01-04), containing naphthalene-substituted amines as an electron donor and cyanoacrylic acid as an electron acceptor, were designed and synthesized, and their photophysical properties and dye-sensitized solar cells (DSCs) performances were characterized. Dyes YF02 and YF04, with 2,6-disubstituted naphthalene frameworks, were superior than their analog dyes YF03 and YF01, having 1,2-disubstituted naphthalene moiety, in incident-photo-to-current conversion efficiency (IPCE) and total solar-to-electric conversion efficiency (η). The DSCs based on YF02, comprised of diphenylamine moiety as the donor, produced the highest η of 5.29% compared to 4.03% of the analog dye YF04, which has pyrrolidine as the donor. Remarkably, a high open-circuit photovoltage (V oc) of 0.799-0.807 V was achieved in the cases of YF02-03, which have diphenylamine-donors. To better understand the structure-property relationship for DSCs application, molecular modelling was performed on YF01-04 and vertical electronic excitations were calculated using long-range corrected energy functional WB97XD and CAM-B3LYP at the basis set level DGDZVP, which were in excellent agreement with the experimental results. Moreover, the equilibrium molecular geometries of dyes YF01-04 were calculated at the density function theory (DFT) level using the hybrid energy functional B3LYP and basis set DGDZVP. The torsion angles () between the naphthalene moiety and diphenylamine donor in YF02 and YF03 were more twisted than that of the pyrrolidine-donor dyes YF01 and YF04, precluding efficient intermolecular π-π charge transfer, which translated into high Voc. Compared to the reference dye TA-St-CA, which is based on diphenylamine as an electron donor linked to a phenyl ring, YF02 achieved higher Voc, which indicated that naphthalene substituted with diphenylamine is more efficient in retarding charge recombinations.