203064-84-0Relevant articles and documents
Early transition metal induced intramolecular cocyclisation / elaboration reactions using a cleavable silicon linker
Probert, Gareth D.,Harding, Ross,Whitby, Richard J.,Coote, Steven J.
, p. 1371 - 1374 (2007/10/03)
1,6- and 1,7-dienes and -enynes incorporating a silicon-oxygen or silicon-nitrogen link are co-cyclised with zirconocene(1-butene) or diisopropoxytitanium(propene) to give metallabicycles. Further elaboration followed by cleavage of the silicon-carbon bond using Tamao oxidation affords a wide variety of organic products.
