2033-49-0Relevant articles and documents
Novel α-Iodination of Ketones Using Iodine/Copper(II) Acetate
Horiuchi, Charles A.,Satoh, James Y.
, p. 312 - 314 (1981)
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A New α-Iodination of Ketones Using Iodine-Ammonium Cerium(IV) Nitrate in Alcohol or Acetic Acid
Horiuchi, C. Akira,Kiji, Shinji
, p. 421 - 426 (2007/10/03)
The direct α-iodination of various ketones using iodine-ammonium cerium(IV) nitrate in acetic acid or alcohol gave the corresponding α-iodo ketones in high yields. The effect of cerium salt on the iodination of ketones, and the iodination of 5α-cholestan-3-one using several methods are also discussed. In the reaction of 3,3,5-trimethylcyclohexanone and unsymmetrical ketones, such as 2-hexanone and 2-heptanone, using methanol, ethanol, 1-propanol, and 2-propanol, the regioselective iodination product was obtained. In the case of bromination, the reaction of ketones with bromine and ammonium cerium(IV) nitrate also yielded the corresponding α-bromo ketones.
Synthesis of α-Iodo Ketones
Sha, Chin-Kang,Young, Jenn-Jong,Jean, Tsong-shin
, p. 3919 - 3920 (2007/10/02)
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