20351-54-6Relevant articles and documents
Method for synthesizing tertiary alcohol by catalytically oxidizing benzyl tertiary C-H bonds of aromatic hydrocarbon through metalloporphyrin
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Paragraph 0068-0069, (2020/09/30)
The invention discloses a method for synthesizing tertiary alcohol by catalytically oxidizing benzyl tertiary C-H bonds of aromatic hydrocarbon through metalloporphyrin. The method comprises the following steps: dispersing metalloporphyrin (1*10-1%, mol/mol) into aromatic hydrocarbon; sealing the reaction system, heating to 40-120 DEG C while stirring, introducing an oxidant (0.10-1.0 MPa), keeping the set temperature and pressure, carrying out reactions for 3.0-24.0 hours under stirring, and carrying out after-treatment on the reaction solution to obtain the product aromatic benzyl tertiary alcohol. The method has the advantages of shortest conversion path, highest atom economy, lower reaction temperature, lower environmental influence and the like, and the selectivity of aromatic benzyl tertiary alcohol is high. In addition, the content of aromatic hydrocarbon hydroperoxide is low, and the safety coefficient is high. The invention provides an efficient, feasible and safe method for synthesizing aromatic benzyl tertiary alcohol through selective catalytic oxidation of benzyl tertiary C-H bonds of aromatic hydrocarbon.
Unusual inhibition effect of 1-(1-naphthyl)-1-methylethylhydroperoxide on the liquid-phase oxidation of isopropylarenes. GC-MS and theoretical studies of the thermal decomposition of 1-naphthyl- and 1-anthryl-1- methylethylhydroperoxides
Mazurkiewicz, Roman,Zawadiak, Jan,Orlinska, Beata,Hefczyc, Barbara,Stec, Zbigniew,Grymel, Miroslawa,Fiedorow, Piotr,Koroniak, Henryk
, p. 289 - 295 (2012/12/22)
All five possible 1-aryl-1methylethylhydroperoxides derived from naphthalene and anthracene were synthesized and their thermal decomposition in GC-MS conditions was investigated to explain the unusual inhibition effect of 1-(1-naphthyl)-1-methylethylhydroperoxide on the liquid-phase oxidation of isopropylarenes. 2-(1-Aryloxy)propenes were identified as the main decomposition products of 1-(1-naphthyl)-1-methylethylhydroperoride and 1-(1-anthryl)-1- methylethylhydroperoxide. The relatively unstable 2-aryloxypropenes have thus far never been described as thermal decomposition products of 1-aryl-1-methylethylhydroperoxides. The plausible mechanism of the formation of 2-(1-aryloxy)propenes was proposed on the basis of AM-1 calculations of the possible rearrangement paths of the alkoxy radicals derived from the investigated hydroperoxides. The mechanism explains the inhibition effect of 1-(1-naphthyl)-1-methylethylhydroperoxide on the oxidation of isopropylarenes.
Alkylnaphthalenes. IX. Photolysis of 2-Isopropylnaphthalene
Honda, Toshiya,Kiyozumi, Morio,Kojima, Shoji
, p. 366 - 371 (2007/10/02)
Photolysis of 2-isopropylnaphthalene (2-IPN) coated on the inner surface of a test tube and on filter paper was examined under irradiation with a high-pressure mercury lamp.The extents of degradation of 2-IPN were about 10 percent after 5 h, about 60 percent after 30 h, and approximately 100 percent after 96 h.Six photoproducts of 2-IPN were identified by means of gas chromatography-mass spectrometry: 2-(2-naphthyl)-2-propanol, 2-isopropenylnaphthalene, 2-acetonaphthalone, β-naphthol, phthalide, and phthalic anhydride, as well as unchanged 2-IPN.The formation pathway of these photoproducts was examined by irradiation of each photoproduct under the same conditions.Keywords- alkylnaphthalene; 2-isopropylnaphthalene; photolysis; high-pressure mercury lamp; photoproduct