20487-40-5 Usage
Description
TERT-BUTYL PROPIONATE, also known as a tertiary ester, is an organic compound derived from propionic acid and tert-butyl alcohol. It is characterized by its stereochemistry, which has been investigated through the kinetic Michael addition of the Z and E lithium enolates. TERT-BUTYL PROPIONATE is known for its potential applications in various industries due to its unique chemical properties.
Uses
Used in Chemical Synthesis:
TERT-BUTYL PROPIONATE is used as an intermediate in the synthesis of various organic compounds for [application reason] its ability to undergo kinetic Michael addition reactions with lithium enolates, allowing for the creation of new molecules with specific stereochemistry.
Used in Pharmaceutical Industry:
TERT-BUTYL PROPIONATE is used as a building block for the development of pharmaceutical compounds for [application reason] its potential to be incorporated into the structure of drugs that target specific biological pathways or receptors.
Used in Research and Development:
TERT-BUTYL PROPIONATE is used as a research compound for [application reason] its unique stereochemistry, which can provide valuable insights into the behavior of similar compounds and their interactions with other molecules.
Used in Solvent Applications:
TERT-BUTYL PROPIONATE is used as a solvent in various chemical processes for [application reason] its ability to dissolve a wide range of substances, making it useful in reactions that require a solvent medium.
Used in Flavor and Fragrance Industry:
TERT-BUTYL PROPIONATE is used as a component in the creation of flavors and fragrances for [application reason] its potential to contribute to the overall scent profile of a product, enhancing its appeal to consumers.
Used in Plastics and Polymers Industry:
TERT-BUTYL PROPIONATE is used as a monomer or additive in the production of plastics and polymers for [application reason] its ability to influence the properties of the final product, such as flexibility, durability, or chemical resistance.
Check Digit Verification of cas no
The CAS Registry Mumber 20487-40-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,0,4,8 and 7 respectively; the second part has 2 digits, 4 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 20487-40:
(7*2)+(6*0)+(5*4)+(4*8)+(3*7)+(2*4)+(1*0)=95
95 % 10 = 5
So 20487-40-5 is a valid CAS Registry Number.
InChI:InChI=1/C7H14O2/c1-5-6(8)9-7(2,3)4/h5H2,1-4H3
20487-40-5Relevant articles and documents
Manganese-Mediated C-C Bond Formation: Alkoxycarbonylation of Organoboranes
Van Putten, Robbert,Filonenko, Georgy A.,Krieger, Annika M.,Lutz, Martin,Pidko, Evgeny A.
supporting information, p. 674 - 681 (2021/04/02)
Alkoxycarbonylations are important and versatile reactions that result in the formation of a new C-C bond. Herein, we report on a new and halide-free alkoxycarbonylation reaction that does not require the application of an external carbon monoxide atmosphere. Instead, manganese carbonyl complexes and organo(alkoxy)borate salts react to form an ester product containing the target C-C bond. The required organo(alkoxy)borate salts are conveniently generated from the stoichiometric reaction of an organoborane and an alkoxide salt and can be telescoped without purification. The protocol leads to the formation of both aromatic and aliphatic esters and gives complete control over the ester's substitution (e.g., OMe, OtBu, OPh). A reaction mechanism was proposed on the basis of stoichiometric reactivity studies, spectroscopy, and DFT calculations. The new chemistry is particularly relevant for the field of Mn(I) catalysis and clearly points to a potential pathway toward irreversible catalyst deactivation.
OXIDATION OF α-DIKETONES BY THE SYSTEM ALUMINUM TRI-tert-BUTYLATE-tert-BUTYL HYDROPEROXIDE
Stepovik, L. P.,Dodonov, V. A.,Smyslova, G. N.
, p. 102 - 106 (2007/10/02)
α-Diketones (butanedione, 2,3-pentanedione, benzil) react with tert-butyl hydroperoxide to form the corresponding anhydrides and tert-butyl alcohol.In the reaction of α-diketones with an oxidative system including aluminum tri-tert-butylate and tert-butyl hydroperoxide, tert-butylacylates and peracylates of the corresponding carboxylic acids are formed as the major reaction products.
