204990-96-5

Basic information

• Product Name: 1-N-trifluoroacetylamino-1,2,3,4,6-pentadeoxy-2β-iodo-6-[trifluoroacetyl-((1R)-phenylethyl)]amino-α-D-hexopyranoside
• CAS NO: 204990-96-5
• Molecular Weight: 552.255
• Mol File: 204990-96-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-N-trifluoroacetylamino-1,2,3,4,6-pentadeoxy-2β-iodo-6-[trifluoroacetyl-((1R)-phenylethyl)]amino-α-D-hexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 1-N-trifluoroacetylamino-1,2,3,4,6-pentadeoxy-2β-iodo-6-[trifluoroacetyl-((1R)-phenylethyl)]amino-α-D-hexopyranoside(204990-96-5)
• EPA Substance Registry System: 1-N-trifluoroacetylamino-1,2,3,4,6-pentadeoxy-2β-iodo-6-[trifluoroacetyl-((1R)-phenylethyl)]amino-α-D-hexopyranoside(204990-96-5)

Safety Data

• Hazardous Substances Data: 204990-96-5(Hazardous Substances Data)

Upstream product

• 354-38-1 2,2,2-trifluoroacetamide 
• 91704-05-1 (2S)-2-[N-trifluoroacetyl-N-((R)-phenylethyl)aminomethyl]-3,4-dihydro-2H-pyran 
• 516-12-1 N-iodo-succinimide 

Relevant articles and documents

Enantiopure D-, L- (and 2-epi-) purpurosamine C-type glycosyl donors from racemic acrolein dimer - Biocatalytic resolution

Both enantiomers of purpurosamine C-type glycosyl donors [(ent)-9, (ent)-10, (ent)-11] and of a 2-azido epimer [(ent)-14] with a modified pattern of protecting groups have been prepared from racemic 3,4-dihydro-2H-pyran-2-carbalde-hyde (acroiein dimer, rac-1, "indirect aziridination", "azidonitration"). In two cases (rac-23β: methyl 6-O-acetyl-2,3,4-trideoxy-2α-trifluoroacetylamino-β-D/L- hexopyranoside, rac-32 : methyl 6-O-acetyl-2β-azido-2,3,4-trideoxy-β-D/L-hexopyranoside), efficient resolution has been achieved biocatalytically.