20516-72-7

Basic information

• Product Name: (As(C₆H₅)3)2Fe(CO)3
• CAS NO: 20516-72-7
• Molecular Weight: 752.356
• Mol File: 20516-72-7.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: (As(C₆H₅)3)2Fe(CO)3(CAS DataBase Reference)
• NIST Chemistry Reference: (As(C₆H₅)3)2Fe(CO)3(20516-72-7)
• EPA Substance Registry System: (As(C₆H₅)3)2Fe(CO)3(20516-72-7)

Safety Data

• Hazardous Substances Data: 20516-72-7(Hazardous Substances Data)

Upstream product

• 315181-26-1 (C₆H₅)CHCHCHN(C₆H₅)*Fe(CO)2(P(C₆H₅)3)=(C₆H₅)CHCHCHN(C₆H₅)Fe(CO)2(P(C₆H₅)3) 
• 74242-48-1 tricarbonyl[(1-4-η)-2-methoxycyclohexa-1,3-diene]iron 
• 603-32-7 triphenyl-arsane 
• 12152-72-6 (cyclohexa-1,3-diene)iron tricarbonyl 
• 12112-97-9 tricarbonyl[(1-4-η)-1,4-diphenyl-1-azabuta-1,3-diene]iron 
• 1352145-92-6 Fe(CO)4(C₆₀) 
• 13463-40-6 iron pentacarbonyl 
• 17685-52-8 triiron dodecarbonyl 
• 38720-22-8 (2-methyl-4-phenyl-1-oxabuta-1,3-diene)tricarbonyliron⁽⁰⁾ 
• 603-36-1 triphenylantimony 

Downstream Products

• 14375-84-9 Fe(CO)4(As(C₆H₅)3) 
• 49655-12-1 trans-Fe(CO)3{P(OPh)3}{P(C₆H₅)3} 
• 188618-32-8 trans-Fe(CO)3(AsPh₃)(P(OPh)3) 
• 188618-34-0 trans-Fe(CO)3(AsPh₃)(P(OEt)3) 
• 188618-33-9 trans-Fe(CO)3(AsPh₃)(P(OMe)3) 
• 85185-81-5 trans-Fe(CO)3(PPh₃)(PPh₂H) 
• 21255-52-7 trans-Fe(CO)₃(triphenylphosphine)₂ 

Relevant articles and documents

Triphenyl-phosphine and -arsine analogues which facilitate the electrospray mass spectrometric analysis of neutral metal complexes

The six triarylphosphines PPhn(C6H4OMe-p)3-n and PPhn(C6H4NMe2-p)3-n (n = 0-3) and the arsine As(C6H4OMe-p)3 (L) have been synthesized and examined for their use in the electrospray mass spectrometric (ESMS) study of metal complexes. This has been tested with selected examples of the complexes [Mo(CO)4L2], [Fe(CO)3L2], [Fe(CO)4L], [Ru3(CO)9L3], cis-[PtCl2L2], [PdCl2L2] and [AuCl(L)]. All of the metal carbonyl complexes of these ligands gave [M + H]+ ions in their spectra, while in contrast the analogous PPh3 complexes do not, suggesting that these electrospray-friendly ligands should be useful for the characterisation of a wide range of complexes by ESMS. The incorporation of the ligands into metal halide complexes however does not allow the observation of [M + H]+ ions, with ions formed by the previously reported halide-loss mechanism being the only ones observed. The Royal Society of Chemistry 1999.

Transition Metal-carbonyl, -hydrido and -η-Cyclopentadienyl Derivatives of the Fullerene C60

Monoadduct derivatives of the fullerene C60, namely 2-C60)>, 2-C60)> (R = H, Bun), 2-C5H5)2(η2-C60)H> and 2-C60)H>, are described.

Hydrido(triphenylsilyl)tetracarbonyliron derivatives with phosphine ligands

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