205757-13-7Relevant articles and documents
Synthesis and Properties of 9-(Tropylidenehydrazono)fluorene and Related Compounds
Minabe, Masahiro,Nozawa, Toshiya,Kurose, Tomoko,Kimura, Takao,Tsubota, Motohiro
, p. 693 - 697 (1998)
9-(Tropylidenehydrazono)fluorene (1) was obtained by a reaction between 9-fluorenone hydrazone and tropylium tetrafluoroborate. ccompanied by 9-fluorenone azine, 9-(benzylidenehydrazono)fluorene, and 9,9-ditropylfluorene. The amination of 1 occurred at the 2-position of the tropylidene moiety. The addition of tosyl isocyanate to 1 gave the [8 +2] cycloadduct at the 2,4,6-cydoheptatrien-1-imine structure.