205987-58-2

Basic information

• Product Name: (+/-)-[(1R,5R)-2-methyl-5-(1-methylvinyl)cyclohex-2-enyl]benzene
• Synonyms: (+/-)-[(1R,5R)-2-methyl-5-(1-methylvinyl)cyclohex-2-enyl]benzene
• CAS NO: 205987-58-2
• Molecular Weight: 212.335
• Mol File: 205987-58-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (+/-)-[(1R,5R)-2-methyl-5-(1-methylvinyl)cyclohex-2-enyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-[(1R,5R)-2-methyl-5-(1-methylvinyl)cyclohex-2-enyl]benzene(205987-58-2)
• EPA Substance Registry System: (+/-)-[(1R,5R)-2-methyl-5-(1-methylvinyl)cyclohex-2-enyl]benzene(205987-58-2)

Safety Data

• Hazardous Substances Data: 205987-58-2(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 119905-76-9 (1S,5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-yl benzoate 
• 73524-01-3 trans-carveol benzoate 
• 934-56-5 trimethyl(phenyl)stannane 
• 780-69-8 triethoxyphenylsilane 

Relevant articles and documents

Stereoselective Phenylation of Allylic Alcohol Derivatives by Palladium-Catalyzed Cross-Coupling with Hypervalent Silicon Complexes

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Palladium-catalyzed arylation of allylic benzoates using hypervalent siloxane derivatives

Palladium-catalyzed cross-coupling of hypervalent arylsiloxane derivatives proceeded in good to excellent yields with allylic benzoates. Arylation occurred with complete inversion of configuration. The scope and limitations of this reaction, an alternative to the Stille coupling, is summarized.