20637-32-5Relevant articles and documents
IONIC HYDROGENATION OF 5,5-DIMETHYL-1,3-DIOXANES
Mironov, I. V.,Kantor, E. A.,Karakhanov, R. A.,Rakhmankulov, D. L.
, p. 991 - 992 (2007/10/02)
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Version: 1.0
Creation Date: Aug 12, 2017
Revision Date: Aug 12, 2017
Product name | 1,3-dimethoxy-2,2-dimethylpropane |
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Product number | - |
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Other names | Propane,1,3-dimethoxy-2,2-dimethyl |
Identified uses | For industry use only. |
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Uses advised against | no data available |
Emergency phone number | - |
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Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
More Details:20637-32-5 SDS
Dimethoxymethane
isobutene
A
2,2-dimethoxypropane
B
1,3-dimethoxy-3-methyl-butane
Conditions | Yield |
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With boron trifluoride at 45℃; |
5,5-dimethyl-1,3-dioxane
trifluoroacetic acid
A
2,2-dimethyl-1,3-propanediol monomethyl ether
B
2,2-dimethoxypropane
C
Trifluoro-acetic acid 3-methoxy-2,2-dimethyl-propyl ester
D
Trifluoro-acetic acid 2,2-dimethyl-3-(2,2,2-trifluoro-acetoxy)-propyl ester
Conditions | Yield |
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With triethylsilane; hydride ion Product distribution; Mechanism; Ambient temperature; without addition of hydride ion; |
Dimethoxymethane
boron trifluoride
isobutene
A
2,2-dimethoxypropane
B
1,3-dimethoxy-3-methyl-butane
Conditions | Yield |
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at 45℃; analoge Reaktion mit Acetaldehyd-diaethylacetal; |
2,2-dimethoxypropane
ethyl (2R,3S,5R)-5-(tert-butyldimethylsilyloxy)-2,3-dihydroxy tetradecanoate
ethyl (4R,5S)-5-((R)-2-(tert-butyldimethylsilyloxy)undecyl)-2,2-dimethyl-1,3-dioxolane-4-carboxylate
Conditions | Yield |
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With CSA In dichloromethane at 0 - 20℃; for 0.5h; Inert atmosphere; | 96% |
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