20684-97-3Relevant articles and documents
Exploring the Reactivity of Donor-Stabilized Phosphenium Cations: Lewis Acid-Catalyzed Reduction of Chlorophosphanes by Silanes
Pearce, Kyle G.,Borys, Andryj M.,Clark, Ewan R.,Shepherd, Helena J.
supporting information, p. 11530 - 11536 (2018/09/21)
Phosphane-stabilized phosphenium cations react with silanes to effect either reduction to primary or secondary phosphanes, or formation of P-P bonded species depending upon counteranion. This operates for in situ generated phosphenium cations, allowing catalytic reduction of P(III)-Cl bonds in the absence of strong reducing agents. Anion and substituent dependence studies have allowed insight into the competing mechanisms involved.
Cleavage of P=O in the presence of P-N: Aminophosphine oxide reduction with in situ boronation of the PIII product
Kenny, Niall P.,Rajendran, Kamalraj V.,Jennings, Elizabeth V.,Gilheany, Declan G.
supporting information, p. 14210 - 14214 (2013/11/06)
In contrast to tertiary phos-phine oxides, the deoxygenation of aminophosphine oxides is effectively impossible due to the need to break the immensely strong and inert P=O bond in the presence of a relatively weak and more reactive P-N bond. This long-sta
Synthesis and binding properties of oligodeoxynucleotides containing phenylphosphon(othio)ate linkages
Mag, Matthias,Muth, Jochen,Jahn, Kerstin,Peyman, Anusch,Kretzschmar, Gerhard,Engels, Joachim W.,Uhlmann, Eugen
, p. 2213 - 2220 (2007/10/03)
A method for the synthesis of chimeric oligodeoxynucleotides comprised of phosphodiester and phenylphosphonate [3'O-P(=O)(C6H5)-O-5'] or phenylphosphono-thioate [3'-O-P(=S)(C6H5)-O-5'] linkages has been develope
