207519-42-4

Basic information

• Product Name: Fe(C₂₂H₂₆N₂O₆)(CO)3
• CAS NO: 207519-42-4
• Molecular Weight: 554.336
• Mol File: 207519-42-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Fe(C₂₂H₂₆N₂O₆)(CO)3(CAS DataBase Reference)
• NIST Chemistry Reference: Fe(C₂₂H₂₆N₂O₆)(CO)3(207519-42-4)
• EPA Substance Registry System: Fe(C₂₂H₂₆N₂O₆)(CO)3(207519-42-4)

Safety Data

• Hazardous Substances Data: 207519-42-4(Hazardous Substances Data)

Upstream product

• 23150-65-4 dimethyl glutamate hydrochloride 

Downstream Products

• 207459-79-8 Fe(C₂₀H₂₂N₂O₆)(CO)3 

Relevant articles and documents

Organometallic complexes of iridium, palladium, chromium and iron from 2-phenyl-5(4H)-oxazolones - Organometallic labelled dipeptides

Reactions of 2-phenyl-4-R-5(4H)-oxazolones (R = Me, CH2Ph, CHMeEt) with [(η5-C5Me5)IrCl2]2 afforded the cyclometallated complexes (η-C5Me5)(Cl)Ir(L) (1-3) [L = 2-phenyl-4-R-5(4H)-oxazolone(C-o,N)], 2-Phenyl-5(4H)-oxazolone reacts with [(η5-C5Me5)IrCl2]2 and palladium(II) acetate to give complexes with a C-o,N-bridging oxazolone [(η5-C5Me5)(Cl)Ir] 2(μ-Cl)(μ-L-H+) (4) and Pd3-ac)5(μ-L-H+) (5). 2-Phenyloxazolone anions were added to the π ligands of [(η5-C6H7)Fe(CO)3]+ and [(η7-C7H7)Cr(CO)3]+ to give the adducts 6-11. Dipeptide derivatives 12-18 were obtained by reaction of 1, 2 and by reaction of the adduct 6 from [(η5-C6H7)Fe(CO)3]+ and the anion of 2-phenyloxazolone with α-amino acid esters. These reactions may be used for the labelling of peptides. Saponification of 15-18 yields the organometallic substituted peptide acids 19-22. Their dianions (deprotonation of COOH and peptide amide) were used as ligands towards (Ph3P)2PtCl2 to yield the bimetallic complexes 23-25. The structures of 4, 5, 9 and 10 were determined by X-ray diffraction.