20802-18-0

Basic information

• Product Name: 4-(3,4-dimethoxy-phenyl)-1-methyl-2,3-dihydro-pyrrole
• Synonyms: 4-(3,4-dimethoxy-phenyl)-1-methyl-2,3-dihydro-pyrrole
• CAS NO: 20802-18-0
• Molecular Weight: 219.283
• Mol File: 20802-18-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 4-(3,4-dimethoxy-phenyl)-1-methyl-2,3-dihydro-pyrrole(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(3,4-dimethoxy-phenyl)-1-methyl-2,3-dihydro-pyrrole(20802-18-0)
• EPA Substance Registry System: 4-(3,4-dimethoxy-phenyl)-1-methyl-2,3-dihydro-pyrrole(20802-18-0)

Safety Data

• Hazardous Substances Data: 20802-18-0(Hazardous Substances Data)

Upstream product

• 2859-78-1 4-Bromoveratrole 
• 872-50-4 1-methyl-pyrrolidin-2-one 
• 85753-65-7 N-[3-Cyano-3-(3,4-dimethoxy-phenyl)-propyl]-N-methyl-benzenesulfonamide 
• 86227-35-2 N-[3-(3,4-Dimethoxy-phenyl)-4-oxo-butyl]-N-methyl-benzenesulfonamide 
• 93-17-4 3,4-dimethoxyphenylacetonitrile 
• 126651-52-3 3-(3,4-Dimethoxy-phenyl)-pyrrolidine-1,2,2-tricarboxylic acid trimethyl ester 
• 126631-71-8 3-(3,4-Dimethoxy-phenyl)-pyrrolidine-1,2-dicarboxylic acid 1-methyl ester 
• 154077-25-5 2-(3,4-Dimethoxy-phenyl)-3-iodo-pyrrolidine-1-carboxylic acid methyl ester 
• 154077-24-4 3-Bromo-2-(3,4-dimethoxy-phenyl)-pyrrolidine-1-carboxylic acid methyl ester 
• 126631-72-9 4-(3,4-Dimethoxy-phenyl)-2,3-dihydro-pyrrole-1-carboxylic acid methyl ester 
• 85753-67-9 N-[3-(3,4-Dimethoxy-phenyl)-3-[1,3]dioxolan-2-yl-propyl]-N-methyl-benzenesulfonamide 
• 88741-39-3 1-methyl-3-(3,4-dimethoxyphenyl)-2-pyrrolidinone 
• 91-16-7 1,2-dimethoxybenzene 

Downstream Products

• 6023-73-0 mesembrine 

Relevant articles and documents

A Convenient Route to β-Aryl-substituted Cyclic Enamines as Key Synthetic Intermediates of Sceletium and Amaryllidaceae Alkaloids

Aryl groups were introduced into the position β to the nitrogen atom of cyclic amines by carrying out the anodic α-methoxylation of cyclic amine derivatives, the elimination of methanol from the oxidized products, the halomethoxylation of the resulting α,β-unsaturated cyclic amine derivatives, the replacement of the α-methoxy group with an aryl group, and the silver ion-promoted migration of the α-aryl group to the β-position, consecutively.This method was applied to the synthesis of some alkaloids such as (+/-)-mesembrine.

SCELETIUM (AIZOACEAE) ALKALOIDS: TOTAL SYNTHESIS OF RACEMIC MESEMBRANONE, MESEMBRENONE, O-METHYLSCELETENONE AND O-METHYL DIHYDROSCELETENONE

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