20894-11-5

Basic information

• Product Name: 1-Pentanone, 4-methyl-4-nitro-1,3-diphenyl-
• CAS NO: 20894-11-5
• Molecular Formula: C18H19NO3
• Molecular Weight: 297.354
• Mol File: 20894-11-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 1-Pentanone, 4-methyl-4-nitro-1,3-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Pentanone, 4-methyl-4-nitro-1,3-diphenyl-(20894-11-5)
• EPA Substance Registry System: 1-Pentanone, 4-methyl-4-nitro-1,3-diphenyl-(20894-11-5)

Safety Data

• Hazardous Substances Data: 20894-11-5(Hazardous Substances Data)

Upstream product

• 20884-21-3 3,4-dihydro-2,2-dimetyl-3,5-diphenyl-2H-pyrrole-1-oxide 
• 79-46-9 2-nitropropane 
• 614-47-1 1,3-diphenyl-propen-3-one 

Downstream Products

• 20884-21-3 3,4-dihydro-2,2-dimetyl-3,5-diphenyl-2H-pyrrole-1-oxide 
• 21200-38-4 2,2-dimethyl-3,5-diphenyl-3,4-dihydro-2H-pyrrole 
• 94-41-7 benzalacetophenone 
• 20894-13-7 (+/-)-5-methyl-5-nitro-4-phenylhexan-2-one 
• 70078-39-6 2,2-dimethyl-3,5-diphenyl-pyrrolidine 
• 13917-67-4 5,5,5',5'-tetramethyl-2,4,2',4'-tetraphenyl-octahydro-[2,2']bipyrrolyl 
• 81113-66-8 2,2,5-Trimethyl-3-phenyl-pyrrolidine 
• 20894-24-0 2,5,5-trimethyl-4-phenyl-3,4-dihydropyrrole 1-oxide 
• 20894-31-9 2,2,5-trimethyl-3-phenyl-3,4-dihydro-2H-pyrrole 
• 70200-79-2 Dimethyl-2,2 diphenyl-3,5 2H-pyrrole 

Relevant articles and documents

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Synthesis of new chiral macrocycles-based glycolipids and its application in asymmetric Michael addition

A series of new mix aza- and thia-macrocyclic glycolipids (9, 10, 16 and 17) have been synthesized and their enantiomeric selectivity was studied. The synthesis of the macrocycles involved a simple protection of two hydroxyl groups of the glycolipids followed by building up the mix-heteroatom macrocyclic in simple sequences. The macrocycles and previously investigated analogues (18, 19, 20 and 21) have been applied as phase transfer catalysts in the enantioselective Michael addition of 2-nitropropane to chalcone and showed good-to-excellent enantiomer excess (ee). Among the catalysts, the galactose aza-crown ether-based glycolipid 21 proved to be the most effective with 90% ee. Graphic abstract: [Figure not available: see fulltext.]

Epi-cinchona based thiourea organocatalyst family as an efficient asymmetric Michael addition promoter: Enantioselective conjugate addition of nitroalkanes to chalcones and α,β-unsaturated N-acylpyrroles

(Chemical Equation Presented) A small set of easily available epi-cinchona based thiourea organocatalysts have been synthesized and tested in enantioselective Michael addition of nitroalkanes to chalcones. These bifunctional catalyst systems promoted the

Henry reaction and 1,4-addition of nitroalkanes to α,β- unsaturated carbonyl compounds under the influence of MS 4 A in DMSO

In the presence of MS 4 A in DMSO (dimethyl sulfoxide), Henry reaction with various carbonyl compounds and nitroalkanes proceeded smoothly to give the corresponding β-nitroalcohol without a base catalyst. Moreover, 1,4-additon of nitroalkane to α,β-unsaturated ketones was also performed in DMSO. Copyright