209287-67-2

Basic information

• Product Name: tris(o-tolyl)antimony diacetate
• CAS NO: 209287-67-2
• Molecular Weight: 513.237
• Mol File: 209287-67-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tris(o-tolyl)antimony diacetate(CAS DataBase Reference)
• NIST Chemistry Reference: tris(o-tolyl)antimony diacetate(209287-67-2)
• EPA Substance Registry System: tris(o-tolyl)antimony diacetate(209287-67-2)

Safety Data

• Hazardous Substances Data: 209287-67-2(Hazardous Substances Data)

Upstream product

• 31219-51-9 tris(2-methylphenyl)stibane oxide 
• 932-31-0 ortho-tolylmagnesium bromide 
• 615-37-2 ortho-methylphenyl iodide 
• 382148-90-5 [(trichloroacetyl)imino]tris(2-methylphenyl)-λ5-stibane 
• 64-19-7 acetic acid 
• 23822-15-3 tri(o-tolyl)antimony 
• 1600-27-7 mercury(II) diacetate 

Downstream Products

• 15286-11-0 diethyl o-tolylphosphonate 
• 91994-11-5 5,5-dimethyl-2-(o-tolyl)-1,3,2-dioxaborinane 
• 75950-75-3 3-(2-methylphenyl)acrylic acid methyl ester 
• 14309-60-5 1-phenylethynyltoluene 

Relevant articles and documents

Pd-catalyzed C-arylation of unsaturated compounds with pentavalent triarylantimony dicarboxylates

Triarylantimony (V) derivatives Ar3SbX2 (X = Hal or acyloxy) were prepared by reaction of Ar3Sb with equimolar amounts of a peroxide ROOH (R = t-Bu, H) in the presence of an acid or an anhydride in good to excellent yields. Ar3Sb(O2CR)2 are mild and efficient C-arylation reagents of unsaturated compounds (methyl acrylate, styrene, 2-phenylpropene and acrylonitrile) under palladium catalysis at 50 °C, with PdCl2 being the most effective catalyst. Ar3SbHal2 do not react under these conditions.