20944-88-1

Basic information

• Product Name: 2-(2-METHYLALLYL)PHENOL
• Synonyms: 2-(2-METHYLALLYL)PHENOL;2-(2-Methyl-2-propenyl)phenol;2-(2-methyl-2-propen-1-yl)phenol
• CAS NO: 20944-88-1
• Molecular Formula: C₁₀H₁₂O
• Molecular Weight: 148.2017
• Mol File: 20944-88-1.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 233.3°Cat760mmHg
• Flash Point: 104.6°C
• Appearance: /
• Density: 0.997g/cm³
• Vapor Pressure: 0.0369mmHg at 25°C
• Refractive Index: 1.538
• PKA: 10.21±0.30(Predicted)
• CAS DataBase Reference: 2-(2-METHYLALLYL)PHENOL(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-METHYLALLYL)PHENOL(20944-88-1)
• EPA Substance Registry System: 2-(2-METHYLALLYL)PHENOL(20944-88-1)

Safety Data

• Hazardous Substances Data: 20944-88-1(Hazardous Substances Data)

Usage

Chemical composition

Consists of a phenol group with a 2-methylallyl side chain attached to the benzene ring.

Usage

Commonly used as a fragrance ingredient and flavoring agent.

Aroma

Has a sweet, floral, and spicy aroma.

Natural sources

Can be found in various sources such as flowers, fruits, and essential oils.

Applications

Utilized in the production of perfumes, soaps, and other cosmetic products.

Potential properties

Studied for its antioxidant and antimicrobial properties.

Industries of value

Has potential applications in the pharmaceutical and food industries.

InChI:InChI=1/C10H12O/c1-8(2)7-9-5-3-4-6-10(9)11/h3-6,11H,1,7H2,2H3

Upstream product

• 108-95-2 phenol 
• 1458-98-6 2-methyl-3-bromo-1-propene 
• 10178-53-7 1-bromo-2-((2-methylallyl)oxy)benzene 
• 33316-80-2 1-(2-hydroxyphenyl)-2-methyl-2-propanol 
• 5820-22-4 methylallyl phenyl ether 
• 91-66-7 N,N-diethylaniline 
• 101-84-8 diphenylether 

Downstream Products

• 861009-82-7 acetic acid-(2-methallyl-phenyl ester) 
• 20944-90-5 allyl-(2-methallyl-phenyl)-ether 
• 6337-33-3 2,2-dimethyl-2,3-dihydro-1-benzofuran 
• 109939-32-4 2-[2,2-dimethyl-3-(2-methyl-2,3-dihydro-benzofuran-2-yl)-propyl]-phenol 
• 4167-75-3 2-isobutylphenol 
• 6395-29-5 2-(2-methyl-1-propenyl)phenol 
• 101266-89-1 (2-methallyl-phenyl)-propyl ether 
• 100863-01-2 butyl-(2-methallyl-phenyl)-ether 
• 1372768-98-3 1-cyanato-2-(2-methylallyl)benzene 
• 1280721-71-2 C₂₀H₁₇NO₂ 
• 113183-73-6 3,5-dinitro-benzoic acid-(2,4-diisobutyl-6-propyl-phenyl ester) 
• 101740-91-4 2-Isobutyl-4-methallyl-6-propyl-phenol 
• 101740-82-3 (2-isobutyl-6-propyl-phenyl)-methallyl ether 
• 101604-14-2 (2-allyl-6-methallyl-phenyl)-methallyl ether 

Relevant articles and documents

-

-

Method for preparing hydrocarbyl phenol by catalytic conversion of phenolic compound in presence of molybdenum-based catalyst

The invention discloses a method for preparing hydrocarbyl phenol by catalytic conversion of a phenolic compound in the presence of a molybdenum-based catalyst. The method comprises mixing a phenoliccompound, a molybdenum-based catalyst and a reaction solvent, adding the mixture into a sealed reactor, feeding gas into the reactor, heating the mixture to 150-350 DEG C, carrying out stirring for areaction for 0.5-2h, then filtering to remove a solid catalyst and carrying out rotary evaporateion to obtain a liquid product. The phenolic compound has a wide source, a cost is low, product alkyl phenol selectivity is high, an added value is high, alcohol or an alcohol-water mixture is used as a reaction solvent, environmental friendliness is realized, pollution is avoided, any inorganic acids and alkalis are avoided in the reaction process, the common environmental pollution problems in the biomass processing technology are solved, the reaction conditions are mild, the process can be carried out at a low temperature, high-efficiency conversion of the reactants can be realized without consuming hydrogen gas and the method is suitable for large-scale industrial trial production.

Development and Mechanistic Study of Quinoline-Directed Acyl C-O Bond Activation and Alkene Oxyacylation Reactions

The intramolecular addition of both an alkoxy and acyl substituent across an alkene, oxyacylation of alkenes, using rhodium catalyzed C-O bond activation of an 8-quinolinyl ester is described. Our unsuccessful attempts at intramolecular carboacylation of ketones via C-C bond activation ultimately informed our choice to pursue and develop the intramolecular oxyacylation of alkenes via quinoline-directed C-O bond activation. We provide a full account of our catalyst discovery, substrate scope, and mechanistic experiments for quinoline-directed alkene oxyacylation.