20963-49-9Relevant articles and documents
Enantioselective synthesis of β-substituted chiral allylic amines: Via Rh-catalyzed asymmetric hydrogenation
Wang, Qingli,Gao, Wenchao,Lv, Hui,Zhang, Xumu
, p. 11850 - 11853 (2016/10/07)
An asymmetric mono-hydrogenation of 2-acetamido-1,3-dienes catalyzed by a Rh-DuanPhos complex has been developed. This approach provides easy access to chiral allylic amines with excellent enantioselectivities and high regioselectivities. The products are valuable chiral building blocks for pharmaceuticals.
2-Silyloxy-1,2-oxazines, a New Type of Acetals of Conjugated Nitroso Alkenes
Tishkov, Alexander A.,Lesiv, Alexey V.,Khomutova, Yulya A.,Strelenko, Yury A.,Nesterov, Ivan D.,Antipin, Michael Yu.,Ioffe, Sema L.,Denmark, Scott E.
, p. 9477 - 9480 (2007/10/03)
3-Alkyl-substituted 1,2-oxazine N-oxides 2 can be selectively transformed into 2-silyloxy-1,2-oxazines 1 upon treatment with silylating reagents. In the solid state derivatives 1 adopt a chair conformation with the pyramidal nitrogen atom, whereas in solu