20992-68-1Relevant articles and documents
REACTIONS EN MILIEU HETEROGENE SOLIDE-LIQUIDE FAIBLEMENT HYDRATE III - LA REACTION DE WITTIG DANS LE SYSTEME CARBONATES ALCALINS/SOLVANT ORGANIQUE PROTIQUE
Le Bigot, Y.,El Gharbi, R.,Delmas, M.,Gaset, A.
, p. 3813 - 3824 (2007/10/02)
The use of alkaline carbonates in a slighty hydrated solid-liquid protic organic media allowed the synthesis of alkenes from polyfunctional aldehydes with high yield in a E preferential stereochemistry specially with non-stabilized ylides.It has been shown that the decomposition of the threo betain acts as the determining step of the reaction.