21019-60-3

Basic information

• Product Name: (Z)-4-methyl-3-hexen-1-ol
• Synonyms: (Z)-4-methyl-3-hexen-1-ol
• CAS NO: 21019-60-3
• Molecular Weight: 114.188
• Mol File: 21019-60-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-4-methyl-3-hexen-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-4-methyl-3-hexen-1-ol(21019-60-3)
• EPA Substance Registry System: (Z)-4-methyl-3-hexen-1-ol(21019-60-3)

Safety Data

• Hazardous Substances Data: 21019-60-3(Hazardous Substances Data)

Upstream product

• 928-97-2 (E)-3-hexen-1-ol 
• 35739-70-9 dimethyldichlorotitanium(IV) 
• 928-96-1 (Z)-3-Hexen-1-ol 

Downstream Products

• 1604805-04-0 C₁₅H₂₀O₃ 
• 1604805-05-1 C₁₃H₁₈O 
• 1604805-06-2 C₁₄H₂₀O 
• 1604805-07-3 C₁₄H₂₀O₂ 
• 1604805-08-4 C₁₄H₂₀O₂ 
• 1604805-09-5 C₂₀H₂₄O₂ 
• 1604805-10-8 C₁₅H₂₂O₃ 
• 1604805-11-9 C₁₆H₂₄O₄ 
• 1604805-12-0 C₁₃H₁₇ClO 
• 1604805-13-1 C₁₃H₁₇ClO 
• 1604805-14-2 C₁₅H₂₀O₃ 
• 1604805-16-4 C₁₄H₂₀O 
• 886-65-7 trans,trans-1,4-Diphenyl-1,3-butadiene 

Relevant articles and documents

TITANIUM-MEDIATED AND NEIGHBORING-GROUP ASSISTED δ-METHYLATION OF HOMOALLYL ALCOHOLS : A NEW REGIO- AND STEREOSELECTIVE CC-LINKING REACTION

Upon treatment with dimethyltitanium dichloride or trimethylaluminium in the presence of titanium tetrachloride, a hydrogen atom at the olefinic 4-position is replaced by a methyl group.Terminal homoallyl alcohols afford (E)-isomers.If the double bond is an internal one, the carbon chain (at the other side of the hydroxy group) leaves its original position to the enterning methyl group and switches to the other one at the same carbon atom.