210228-13-0Relevant articles and documents
Palladium-catalyzed salt-free double decarboxylative aryl allylation
Daley, Ryan A.,Topczewski, Joseph J.
, p. 1709 - 1713 (2019/02/20)
This report describes a palladium-catalyzed decarboxylative aryl allylation between unactivated benzoic acids and allylic carbonates. This transformation successfully couples a variety of carbonates and benzoic acids in good yield (up to 94%) using 1 mol% palladium. This salt free allyl-arylation proceeds without added base, copper, or silver. The only stoichiometric byproducts are carbon dioxide and tert-butanol.
A hyperbranched aromatic fluoropolyester for photonic applications
Kang, Seok Ho,Luo, Jingdong,Ma, Hong,Barto, Richard R.,Frank, Curtis W.,Dalton, Larry R.,Jen, Alex K.-Y.
, p. 4355 - 4359 (2007/10/03)
A highly fluorinated hyperbranched aromatic polymer was prepared by a mild one-step polyesterification of an AB2 type monomer at room temperature using dicyclohexylcarbodiimide and 4-(dimethylamino)pyridium 4-toluenesulfonate as the condensatio